نتایج جستجو برای: selective adsorption

تعداد نتایج: 251740  

Journal: :Physical review letters 2004
Thorsten Bogner Andreas Degenhard Friederike Schmid

We investigate the mechanisms underlying selective molecular recognition of single heteropolymers at chemically structured planar surfaces. To this end, we study systems with two-letter (HP) lattice heteropolymers by exact enumeration techniques. Selectivity for a particular surface is defined by an adsorption energy criterion. We analyze the distributions of selective sequences and the role of...

2016
Zhiguo Xie Xiaoxia Zhou Huixia Wu Lisong Chen Han Zhao Yan Liu Linyu Pan Hangrong Chen

A series of CuBi co-doped mesoporous zeolite Beta (CuxBiy-mBeta) were prepared by a facile one-pot hydrothermal treatment approach and were characterized by XRD, N2 adsorption-desorption, TEM/SEM, XPS, H2-TPR, NH3-TPD and in situ DRIFTS. The catalysts CuxBiy-mBeta were applied to the removal of NOx by selective catalytic reduction with ammonia (NH3-SCR), especially the optimized Cu1Bi1-mBeta ac...

Journal: :Molecules 2017
Shengjie Wu Mingjin Xie Qin Zhang Lijiang Zhong Muhan Chen Zhangjie Huang

Conventional separation methods are not suitable for recovering palladium present in low concentrations in ore leaching solutions. In this study, a novel isopentyl sulfide (S201)-impregnated α-MnO₂ nanorod adsorbent (BISIN) was prepared, characterized, and applied for the selective adsorption and separation of palladium from the leaching liquor of ores. Batch studies were carried out, and the m...

Journal: :Physical chemistry chemical physics : PCCP 2014
Constantinos D Zeinalipour-Yazdi David J Willock Andreia Machado Karen Wilson Adam F Lee

Crotonaldehyde (2-butenal) adsorption over gold sub-nanometer particles, and the influence of co-adsorbed oxygen, has been systematically investigated by computational methods. Using density functional theory, the adsorption energetics of crotonaldehyde on bare and oxidised gold clusters (Au13, d = 0.8 nm) were determined as a function of oxygen coverage and coordination geometry. At low oxygen...

2017
AKIRA SUZUKI KAZUKI YASUHARA HIDESHI SEKI HIDEO MARUYAMA Akira Suzuki

A fundamental study about the selective foam separation of protein mixture was carried out. A solution containing two proteins, Ovalbumin (OA) and Lysozyme (LZ), and an anionic surfactant, Sodium Dodecyle Sulfate (SDS), was adjusted to pH 6.0 which refered to an intermediate state between the isoelectric points of the proteins. The solution was processed by continuous foam separation. The resul...

Journal: :Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 2017
Xiaoxia Li Kyung Ho Row

Deep eutectic solvents (DES) are potential ecofriendly surfactants for the preparation of materials. In this study, both molecularly imprinted polymers (MIPs) and mesoporous siliceous materials (MSMs) were modified by betaine-based DES. Six materials were employed as solid phase extraction (SPE) adsorbents for the rapid purification of levofloxacin. The DES-based materials showed better selecti...

Journal: :Applied and environmental microbiology 2005
Munehiro Kubota Masayoshi Matsui Hiroyuki Chiku Nobuyuki Kasashima Manabu Shimojoh Kengo Sakaguchi

Cell adsorption and selective desorption for separation of microbial cells were conducted by using chitosan-immobilized silica (CIS). When chitosan was immobilized onto silica surfaces with glutaraldehyde, bacterial cells adsorbed well and retained viability. Testing of the adsorption and desorption ability of CIS using various microbes such as Escherichia coli, Aeromonas hydrophila, Pseudomona...

Journal: :Journal of the American Chemical Society 2014
Kyuho Lee William C Isley Allison L Dzubak Pragya Verma Samuel J Stoneburner Li-Chiang Lin Joshua D Howe Eric D Bloch Douglas A Reed Matthew R Hudson Craig M Brown Jeffrey R Long Jeffrey B Neaton Berend Smit Christopher J Cramer Donald G Truhlar Laura Gagliardi

Gas separations with porous materials are economically important and provide a unique challenge to fundamental materials design, as adsorbent properties can be altered to achieve selective gas adsorption. Metal-organic frameworks represent a rapidly expanding new class of porous adsorbents with a large range of possibilities for designing materials with desired functionalities. Given the large ...

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