The intrinsic electrocatalytic properties of functionalized graphene sheets (FGSs) in nitric oxide (NO) sensing are determined by cyclic voltammetry with FGS monolayer electrodes. The degrees of reduction and defectiveness of the FGSs are varied by employing different heat treatments during their fabrication. FGSs with intermediate degrees of reduction and high Raman ID to IG peak ratios exhibi...

6-Phosphate aminopurine (PA), a purine analog, is usually used in clinical anticancer treatment and biochemical research. Up to now, to the best of our knowledge, no literature about the electrochemical behaviors of PA has been reported. In this study, nano-p–n junction heterostructures based on TiO2 nanobelts were produced by the assembly of p-type semiconducting NiO nanoparticles onto the n-t...

In this work, hierarchical WO3 core-shell microspheres were synthesized via a facile template-free precipitation method. Gas sensing properties of the synthesized powder to acetone and some other volatile organic compounds were comparatively investigated with commercial WO3 nanoparticles. The synthesized and commercial powders were characterized by X-ray diffraction, scanning electron microscop...

Metal nanoparticles decorated single-walled carbon nanotubes (SWNTs) can lead to considerable enhancement in sensing performance towards different gas analytes, however the sensing mechanism was not clearly elucidated. The detailed sensing mechanism of hybrid gold-SWNT nanostructures toward hydrogen sulfide was investigated using field effect transistor (FET) transfer characteristics. At low H2...

Enzyme modified electrodes were fabricated with poly(aniline-co-maminophenol). Electrochemical polymerization of aniline and m-aminophenol was performed to get the film of copolymer on the surface of gold electrode. Modified electrodes were fabricated by two methods, physical entrapment and covalent cross-linking. In one of the method, gold nanoparticles were loaded into the copolymer film and ...

The use of nanopillar array electrodes (NAEs) for biosensor applications was explored using a combined experimental and simulation approach to characterize the role of reaction kinetics and mass transport in glucose detection with NAEs. Thin gold electrodes with arrays of vertically standing gold nanopillars were fabricated and their amperometric current responses were measured under bare and f...

Polymer membrane electrodes operated by pulsed chronopotentiometry have recently been introduced to replace traditional ion-selective electrodes for a number of applications. While ion-selective electrodes for the polycation protamine have been reported, for instance, a pulsed chronopotentiometric readout mode (called here pulstrode) provides improved stability and reproducibility while exhibit...

This work aims to obtain the capacitance resulted from the coplanar electrode configuration meant to be used for underwater sensing application. Coplanar structure is proposed to overcome the complexity of parallel electrode microfabrication processes which require repeating process of layer deposition. Work is achieved through Finite Element Model (FEM) using ANSYS 12.1 and the result is compa...

This paper presents a transparent microfluidic chip designed for continuous-flow photochemistry applications with integrated electrical sensing. The transparent chip design allows for microscale photochemistry, and permits direct, real-time visual/electrical observation. The microchip uses optically transparent indium tin oxide (ITO) electrodes for reagent and phase tracking. High-speed videogr...

ii To my family iii ACKNOWLEDGEMENTS First of all, I would like to thank my academic advisor Professor Weng Poo Kang for his assistance, guidance and encouragement through my studies at Vanderbilt University. I would also like to thank to Supil Raina for his advisory support. Finally, I would like to thank to my dear parents and brother for their continuous and sincere support.