An interesting aminosilanetrithiol RSi(SH)3 (R = N(SiMe3)-2,6-iPr2C6H3) has been prepared by the reaction of lithium aminosilanetrithiolate {RSi[SLi(THF)]3}2 with MeCOOH. Theoretical calculations indicate that the LP(N) → σ*(Si-S) and LP(S) → σ*(Si-S) electron donations remarkably contribute to the stabilization of the Si(SH)3 part of the molecule. RSi(SH)3 is the first example of a stable mole...

The functionalization of elastomers by phosphonate groups remains relatively unexplored considering the great potential these polymers would represent for applications. In this paper, thiol-functional oligophosphonates were designed and coupled a thiol-ene reaction to styrene-butadiene rubber (SBR). We adopted RAFT methodology with dimethyl vinylphosphonate (DMVP) high-temperature thermolysable...

The production, optimisation and partial characterisation of xylanases from newly isolated wild strains of Coprinellus disseminatus was performed in solid-state fermentation. Strains SH-1 and SH-2 showed high xylanase (727.78 and 227.99 IU/mL) with very low CMCase (0.925 and 0.660 IU/mL) and laccase (0.640 and 0.742 U/mL) activities at incubation time seven days, 37 degrees C and initial pH 6.4...

The second harmonic (SH) generation from the highly epitaxial Al-doped ZnO film on sapphire was measured, using the femtosecond Ti:Sapphire laser at the near-resonant SH wavelength, in reflection geometry to avoid the sapphire's contribution in the conventional Maker fringes technique. By investigating SH intensities as a function of the azimuthal angle along the film's normal, we found that th...

This study examines the temporal evolution of the tropospheric circulation following large-amplitude variations in the strength of the Southern Hemisphere (SH) stratospheric polar vortex in data from 1979 to 2001 and following the SH sudden stratospheric warming of 2002. In both cases, anomalies in the strength of the SH stratospheric polar vortex precede similarly signed anomalies in the tropo...

This cross-sectional study examined differences in children's health behaviors during school term (ST) versus school holiday (SH: June-July) and how associations changed when weather characteristics were considered. Children aged 5-18 years (n = 406) from a subtropical climate reported behaviors over 20 months. Multivariable regression models controlling for age, sex, race and body mass index z...

Natural product curcumin (Cur) and H2S-releasing prodrug SH-aspirin (SH-ASA) are potential anticancer agents with diverse mechanisms, but their clinical application prospects are restricted by hydrophobicity and limited efficiency. In this work, we coencapsulated SH-ASA and Cur into methoxy poly(ethylene glycol)-poly (lactide-coglycolide) (mPEG-PLGA) nanoparticles through a modified oil-in-wate...

Two thousand three hundred and seventy strains of Shigella dysenteriae, Sh flexneri, and Sh boydii isolated in England and Wales from 1974 to 1978 were tested for resistance to 12 antimicrobial drugs. Eighty per cent of strains were resistant to one or more drugs, with sulphonamide resistance occurring most frequently. Resistance to streptomycin, tetracycline, ampicillin, and chloramphenicol in...

introduction: the purpose of this study was to compare the antimicrobial efficacy of sodium hypochlorite (sh) and calcium hypochlorite (ch) against enterococcus faecalis (e. faecalis) using quantitative real-time polymerase chain reaction (qpcr) analysis and also to compare their cytocompatibility on l929 murine fibroblasts using mossman’s tetrazolium toxicity (mtt) assay. methods and materials...