Magnetic nanoparticles for applications in separation and purification processes must satisfy several basic requirements. They should be superparamagnetic, i.e. possess low coercivity (H c ) and low retentivity (M r ), to enable re-dispersion after magnetic capture. In this study, the synthesis of SiO 2 coated γ-Fe 2 O 3 nanocomposite particles has been attempted to achieve the above magnetic p...

The interaction of chromium oxide with different titania-silica supports has been examined. The oxide supports investigated consisted of SiO,, TiO, , physical mixtures of TiO, and SiO,, a surface titania overlayer on SiO, (10% of theoretical monolayer) and a surface silica overlayer on TiO, (80% of theoretical monolayer). The supported chromium oxide catalysts were structurally characterized wi...

The synthesis and structure of a dimeric aluminium hydroxide complex containing the novel chelating 1,4-disiloxide ligand [CH(2){Me(Me(3)Si)(2)Si}(2)SiO](2)(2-) (2)-2H is reported. [CH(2){Me(Me(3)Si)(2)Si}(2)SiO](2)AlOH (4) was prepared by careful hydrolysis of [CH(2){Me(Me(3)Si)(2)Si}(2)SiO](2)AlMe·THF (3).

New interferometric observations of SiO J =5→ 4 circumstellar line emission around the carbon star IRC+10216, using the Submillimeter Array, are presented. Complemented by multi-transition single-dish observations, including infrared observations of ro-vibrational transitions, detailed radiative transfer modelling suggests that the fractional abundance of SiO in the inner part of the envelope, ...

The orofacial sensorimotor cortex is known to play a role in motor learning. However, how motor learning changes the dynamics of neuronal activity and whether these changes differ between orofacial primary motor (MIo) and somatosensory (SIo) cortices remain unknown. To address these questions, we used chronically implanted microelectrode arrays to track learning-induced changes in the activity ...

We have mapped the SiO J=5–4 line at 217GHz from the HH2̇11 molecular outflow with the Submillimeter Array (SMA). The high resolution map (1.6×0.9) shows that the SiO J=5–4 emission comes from the central narrow jet along the outflow axis with a width of ∼0.8 (∼ 250AU) FWHM. The SiO jet consists of a chain of knots separated by 3–4 (∼ 1000AU) and most of the SiO knots have counterparts in shocke...

A hybrid of Ag nanoparticle (NP)-embedded thin silica-coated graphene oxide (GO@SiO₂@Ag NPs) was prepared as a surface-enhanced Raman scattering (SERS) substrate. A 6 nm layer of silica was successfully coated on the surface of GO by the physical adsorption of sodium silicate, followed by the hydrolysis of 3-mercaptopropyl trimethoxysilane. Ag NPs were introduced onto the thin silica-coated gra...

Solid-state nanopores fabricated by a high-intensity electron beam in ceramic membranes can be fine-tuned on three-dimensional geometry and composition by choice of materials and beam sculpting conditions. For similar beam conditions, 8 nm diameter nanopores fabricated in membranes containing SiO(2) show large depletion areas (70 nm in radius) with small sidewall angles (55 degrees ), whereas t...

A series of V205/TiO 2/SiO 2 catalysts were structurally investigated by in situ Raman spectroscopy and chemically probed by methanol oxidation in order to determine the molecular structure-reactivity relationships of the V205/TiO 2/SiO 2 catalysts. Only surface TiO,. species are present on the 3% TiO 2 /S iO 2 catalysts, and the surface TiO x species as well as bulk TiO 2 (anatase) particles c...

After first investigations on the room temperature photoluminescence (PL) signal of porous Si [1,2], interest in the optical properties of semiconductor nanoparticles, especially porous Si and Si nanoparticles, has grown over the last decade [3,4]. Different processes for the synthesis of nanocrystalline Si (nc-Si) like Si ion implantation into high quality oxides [3], sputtering of Si-rich oxi...