Using the particle-resolved aerosol model PartMC-MOSAIC, we simulate the heterogeneous oxidation of a monolayer of polycyclic aromatic hydrocarbons (PAHs) on soot particles in an urban atmosphere. We focus on the interaction of the major atmospheric oxidants (O3, NO2, OH, and NO3) with PAHs and include competitive co-adsorption of water vapour for a range of atmospheric conditions. For the firs...

We characterize a representative haze event from a series of periodic particulate matter (PM) episodes that occurred in Shanghai during winter 2014. Particle size distribution, hygroscopicity, effective density and effective density single particle mass spectrometry were measured determined online, along with offline analysis of water-soluble inorganic ions and single particle mass spectrometry...

Soot particles can significantly influence the Earth’s climate by absorbing and scattering solar radiation as well as by acting as cloud condensation nuclei. However, despite their environmental (as well as economic and political) importance, the way these properties are affected by atmospheric processing of the combustion exhaust gases is still a subject of discussion. In this work, individual...

The structure of soot was investigated within the fuel-lean (overfire) region of overventilated buoyant turbulent diffusion flames burning in still air. The study was limited to the long residence time regime where characteristic flame residence times are roughly more than an order of magnitude longer than the laminar smoke point residence time and soot generation factors (the mass of soot emit...

The use of alternative fuels, such as bio-alcohols, in advanced propulsion systems could a feasible strategy to address several the current issues associated internal combustion engines fuelled by carbonaceous fossil fuels. Particularly, soot particles, are one key pollutants emitted from compression ignition engines. Therefore, development formation prediction models providing new understandin...

Carbonaceous soot produced in a small diesel engine test facility was investigated with ultra-small-angle X-ray scattering. Three soot samples produced using a reference diesel fuel and the reference fuel plus two oxygenate additives were investigated. The presence of objects at three typical size ranges, i.e., aggregates, primary particles, and subunits, was observed. By studying soot powders ...

An important source of uncertainty in radiative forcing by absorbing aerosol particles is the uncertainty in their morphologies (i.e., the location of the absorbing substance on/in the particles). To examine the effects of particle morphology on the response of an individual black carbon-containing particle in a Single-Particle Soot Photometer (SP2), a series of experiments was conducted to inv...

THE RAYLEIGH limit of the classical Lorenz-Mie (LM) theory is widely utilized in thermal radiation when the particle diameter is small relative to the wavelength of radiation [I+]. This approximation is usually assumed to be accurate up to the size parameter CI = nD/I 2 0.3, D being the particle diameter, i; the wavelength of radiation. The extension of Rayleigh bound from GI 1 0.3 to o[ g 0.8 ...