The crystal structures of yellow Cu3PS4 and of black Cu3SbS4 were refined from single crystal X-ray diffraction data. Cu3PS4 crystallizes orthorhombic in an ordered wurtzite superstructure type with the space group Pmn21 (no. 31), a 1⁄4 7.282(1) A, b 1⁄4 6.339(1) A, c 1⁄4 6.075(1) A, V 1⁄4 280.38(8) A3, and Z 1⁄4 2. The refinement converged to R 1⁄4 0.0276, and wR2 1⁄4 0.0710 for 737 unique ref...