In the article, in order to evaluate effect of various factors on oxidation process n-butane, a series experiments were conducted at temperature 170 ℃ for 58 hours with mixing reactants reactor speed 0.05 m amplitude 2s-1. Infrared spectroscopy, transmission electron microscopy, and powder X-ray diffraction data reported. According infrared when ratio tetra-Npropylammonium hydroxide/tetraethoxy...

The formation of different complexes in aqueous solutions is an important step in understanding the behavior of zinc chloride in water. The structure of concentrated ZnCl2 solutions is governed by coordination competition of Cl(-) and H2O around Zn(2+). According to the solid-liquid phase diagram, the title compounds were crystallized below room temperature. The structure of ZnCl2·2.5H2O contai...

The title compound, Li3AsS4·8H2O, is built up from infinite cationic [Li3(H2O)8](3+) chains which extend along [001] and are cross-linked by isolated tetra-hedral AsS4 (3-) anions via O-H⋯S hydrogen bonds. Two Li and two As atoms lie on special positions with site symmetries -1 (1 × Li) and 2 (1 × Li and 2 × As). The [Li3(H2O)8](3+) chain contains four independent Li atoms of which two are in o...

The new complexes tetra-platinum(II)-thiopyridylporphyrin 3 and tetra-platinum(II)-thiopyridylporphyrinato Zn(II) 4 were obtained by coordination of the peripheral thiopyridyl units of the free-base 5,10,15,20-tetrakis[2,3,5,6-tetrafluoro-4-(4-pyridylsulfanyl)phenyl]porphyrin 1 or their corresponding zinc complex 2, respectively, with four chloro(2,2'-bipyridine)platinum(II) [Pt(bpy)Cl](+) unit...

The comparative study of the spectral-luminescent properties hydrophilic 21-thia-5,10,15,20-tetra-(4-sulfonatophenyl)-porphyrin and 5,10,15,20-tetra-(4-sulfonatophenyl)-porphyrin is carried out in solutions at 293 K. peculiarities halochromic effects have been revealed for first time, which were due to replacement pyrrole ring by thiophene macrocycle. It found that multicenter interactions&#x0D...

The title acetone solvate, C(42)H(28)O(2)·C(3)H(6)O [systematic name: 1,3,10,12-tetra-phenyl-19,20-dioxapenta-cyclo-[10.6.2.0(2,11).0(4,9).0(13,18)]icosa-2(11),3,5,7,9,13,15,17-octa-ene acetone monosolvate], is a photooxygenation product of rubrene (systematic name: 5,6,11,12-tetra-phenyl-tetra-cene). The mol-ecule bends at the bridgehead atoms, which are linked by the O-O transannular bond, wi...

The asymmetric unit of the title compound, (C(13)H(17)N(2)O)(2)[ZnCl(4)]·2H(2)O, contains two tetra-hydro-harmine cations, one tetra-chloro-zincate(II) anion and two water mol-ecules. In the cations, the two 1H-indole ring systems are essentially planar, with maximum deviations of 0.016 (2) and 0.018 (2) Å, and both tetra-hydro-pyridinium rings show a half-chair conformation. The Zn(II) complex...