Poly(vinylidene fluoride) (PVDF) nanocomposites are recently gaining importance due to their unique dielectric and electroactive responses. In this study, GeO2 nanoparticles/PVDF and SiO2 nanoparticles/PVDF nanocomposite films were prepared by a simple solution casting technique. The surface morphology and structural properties of the as-prepared films were studied by X-ray diffraction, scannin...

ABSTRACT: The use of new compounds to increase the shelf life of more perishable foods based on nanoparticles and biodegradable polymers have been developed in packaging. Chitosan (Cts) is a natural biopolymer with excellent biodegradability and nontoxicity and antibacterial effect. In this research antibacterial copper nanoparticles (CuNPs) were incorporated in the biodegradable chitosan matri...

The efficient synthesis of all-acrylic, film-forming, core-shell colloidal nanocomposite particles via in situ aqueous emulsion copolymerization of methyl methacrylate with n-butyl acrylate in the presence of a glycerol-functionalized ultrafine silica sol using a cationic azo initiator at 60 °C is reported. It is shown that relatively monodisperse nanocomposite particles can be produced with ty...

This paper characterizes the fracture toughness of layer-by-layer (LBL) manufactured thin films with elastic polyurethane, a tough polymer, and poly(acrylic acid) as a stiffening agent. A single-edge-notch tension (SENT) specimen is used to study mode I crack propagation as a function of applied loading. Experimental results for the full-field time histories of the strain maps in the fracturing...

This paper describes the application of electrical impedance tomography (EIT) to demonstrate the multifunctionality of carbon nanocomposite thin films under various types of environmental stimuli. Carbon nanotube (CNT) thin films are fabricated by a layer-by-layer (LbL) technique and mounted with electrodes along their boundaries. The response of the thin films to various stimuli is investigate...

Zinc oxide/polyaniline (ZnO/PANI) nanocomposite film is prepared by a chemical method using CuSO4 as redox initiator. The nanocomposite is characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and TG techniques. X-ray diffraction studies of the composite show the reflection of ZnO nanoparticles along with a broad peak of PAN...

Thin films in the Ti-Pt-C system were deposited by non-reactive, DC-magnetron sputtering. Samples were characterised using X-ray photoelectron spectroscopy, X-ray diffraction, and transmission electron microscopy. A previously not reported metastable solid solution carbide, (Ti1xPtx)Cy with a Pt/Ti ratio of up to 0.43 was observed. This solid solution phase was present both as single phase in p...

barbari is a common iranian flat bread that has a short shelf life. the effect of low density polyethylene/clay nanocomposite film was investigated for the package and shelf life of the flat bread when stored at different temperatures and relative humilities with different percentages of nanoparticles. nanoclay concentrations of 2% and 6% were used for the nanocomposite and pure polyethylene wa...

Poly(vinyl alcohol) (PVA)-montmorillonite (MMT) clay nanocomposite films up to 10 wt% clay concentration were synthesized by aqueous solution grown technique. The relative complex dielectric function, alternating current electrical conductivity, electric modulus and impedance properties of these organic-inorganic nanocomposites were investigated in the frequency range from 20 Hz to 1 MHz at amb...

Mass transfer in nanocomposite hydrogel thin films consisting of alternating layers of an organometallic redox polymer (RP) and oxidoreductase enzymes was investigated. Multilayer nanostructures were fabricated on gold surfaces by the deposition of an anionic self-assembled monolayer of 11-mercaptoundecanoic acid, followed by the electrostatic binding of a cationic redox polymer, poly[vinylpyri...