Conductive polymers are a new class of materials, which exhibit highly reversible redox behavior and unusual combination of properties of metals and plastics. The conductivity of a polymer can be increased several-fold by doping it with a suitable dopant. Doping plays a very important role to convert the polymer into conductive form. In this work an attempt has been made to synthesize polyanili...

Abstract The peracetalization of a β-hydroxy hydroperoxide derived from methyl oleate was studied using benzaldehyde as model substrate to give the corresponding fatty 1,2,4-trioxane. desired product obtained mixture regioisomers but only one diastereoisomer each formed. nature acid catalyst and both p-toluene sulfonic (PTSA) Amberlyst A35 (A35) were found be efficient homogeneous heterogeneous...

Jatropha curcas oil is one of interesting renewable resources for preparation biolubricants. However, direct application this as a biolubricant restricted due to its low oxidative stability. This drawback can be overcome by molecule structural redesign through chemical modification process at unsaturated functional groups. was modified via epoxidation, ring opening and esterification processes....

Pretreatment is a necessary step to converting lignocellulosic biomass from its native form into more accessible for the value-added utilization of main components. Herein, we developed one-step acid bleachable pretreatment method using recyclable hydrotrope (p-toluenesulfonic acid, p-TsOH) and chlorate achieve fibers bleaching lignin extraction simultaneously. Under condition p-TsOH concentrat...

Carbazole was oxidized by benzoyl peroxide in presence of p-toluenesulfonic acid to polycarbazole salt at room temperature for the first time. Polycarbazole salts were synthesized via solution and emulsion polymerization pathways. Polycarbazole bases were prepared by dedoping from polycarbazole salts. Formation of polycarbazoles was confirmed from infrared, electronic absorption and EDAX spectr...

The reaction between phenothiazine and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) in the presence of p-toluenesulfonic acid in chloroform was investigated by potentiometry, voltammetry and spectrophotometry, and the reaction pathways were proposed. The conditions for the oxidimetric titration of phenothiazines with a standard chloroform solution of DDQ were optimized and the potentiometric...

A novel series of mesotetrakis[aryl]-21H,23H-porphyrin derivatives 2a-j was synthesized from the condensation of aldehyde derivatives 1a-j with pyrrole in the presence of p-toluenesulfonic acid. The synthesized porphyrins were considered as a model to study the free radical-induced damage of biological membranes and the protective effects of these porphyrins. It was found that these compounds e...