Introduction: Various surface treatments have been used to improve the adhesion of resin cement to zirconia restorations. The present study aimed to investigate the effects of different surface treatments on the bond strength of resin cement to zirconia (Y-TZP) in clinical practice. Methods: thirty square Y-TZP samples were classified into three groups of 10, including group SB (50 µm sandblast...

We present the results of a plane wave based density functional study of the structure and properties of tetragonal zirconia in the range of pressures from 0 to 50 GPa. We predict a transition to a fluorite-type cubic structure at 37 GPa which is likely to be of a soft mode origin and is accompanied by a power law decrease of the frequency of the Raman-active A(1g) mode. A detailed study of the...

We evaluated the biological effects of implant abutments made from ceria-stabilized zirconia/alumina nanocomposite (Ce-TZP/Al2O3) with surface roughness variations using human gingival fibroblasts (HGF-1) in transmucosal region. Two types titanium (Ti) and Ce-TZP/Al2O3 disks different profiles were prepared (Ra0.9 Ra0.02). Surface properties SEM, EDX, wettability analysis. Biological parameters...

In this work nanoscale features that are of importance in the stability yttria-stabilized tetragonal zirconia (Y-TZP) quantified through atom probe tomography . In-depth analysis grain boundary chemistry revealed preferential segregation lighter and smaller ions towards specific boundaries. The relationship between elemental local atomistic structure is investigated at sub-nanometer level to ga...

Objectives: Although implant abutments made of yttria-stabilized tetragonal zirconia polycrystal (3Y-TZP) show great predictability, some issues related to its aging require further study. The objective of this in vitro study is to assess the stability of 3Y-TZP zirconia implant abutments with two different implant connections when subjected to aging simulation through thermocycling and mechani...

A series of ceria nanocatalysts have been prepared to study the structure dependency of the CO oxidation reaction. The ceria samples with well-defined nanostructures (nanocubes/Ce-NC and nanorods/Ce-NR) have been prepared using the hydrothermal method. Mesoporous ceria (Ce-MES) and ceria synthesized with solution combustion technique (Ce-SCS) have also been prepared for comparison. The lowest C...

OBJECTIVES To evaluate the bonding of resin-cement to yttria-stabilized tetragonal zirconia polycrystal (Y-TZP) via silica coating followed by silanization, and three one-bottle universal adhesives, with or without prior conditioning using a zirconia primer. METHODS Y-TZP specimens (n=160) were conditioned by tribochemical silica coating and silanization (CS), or alumina sandblasting with one...

It has recently been reported that in the Y203-stabilized tetragonal zirconia phase (TZP) system the addition of a small amount of transition-metal oxides (e.g. CuO, MnO and ZnO) which form a liquid or amorphous grain boundary phase significantly enhances superplasticity [1, 2]. In CuO-added 2Y-TZP abrupt changes have been found in the stress exponent and activation energy across the melting te...