The oxygen-tolerant radical copolymerization of fluorinated monomers with vinyl ethers at room temperature in the presence a tri-nbutylborane methoxypropylamine (TBB-MOPA)/CH3COOH system is presented. combination commercially available fluoroolefins (FO) [perfluoromethyl ether (PMVE) and hexafluoropropylene (HFP)] (VE) [ethyl (EVE) 2-(perfluorohexyl)ethyl (FAVE6)] was used for synthesis differe...