Metastable scheelite EuVO4 was stabilized by a high temperature and pressure method, which was transformed into a stable zircon phase by annealing treatment in air. Scheelite EuVO4 gave strong emissions with a dominant peak at 617 nm associated with the D0F2 transition of Eu . Eu Mössbauer spectra indicated that the isomer shift for the metastable scheelite phase was ca. 0.5 mm/s lower than tha...

The D’Entrecasteaux Islands of south-eastern Papua New Guinea are active metamorphic core complexes that formed within a region where the plate tectonic regime has transitioned from subduction to rifting. While rapid, post 4 Myr exhumation and cooling of amphibolite and greenschist facies rocks that constitute the footwall of the crustal scale detachment fault system have been previously docume...

In situ LA-MC-ICP-MS U-Pb zircon geochronology combined with cathodoluminescence imaging were carried out to determine protolith and metamorphic ages of orthogneisses from the Western Tatra Mountains (Central Western Carpathians). The metamorphic complex is subdivided into two units (the Lower Unit and the Upper Unit). Orthogneisses of the Lower Unit are mostly banded, fine- to medium-grained r...

The composition of igneous rocks in the continental crust has changed throughout Earth's history. However, the impact of these compositional variations on chemical weathering, and by extension on seawater and atmosphere evolution, is largely unknown. We use the strontium isotope ratio in seawater [(87Sr/86Sr)seawater] as a proxy for chemical weathering, and we test the sensitivity of (87Sr/86Sr...

thoritc and, from the results of infra-red absorption spectra, concluded that this material contained (oH) groups; however, Mumpton and Roy (1961) in their experiments found no evidence in support of this substitution. rn the course of an extensive study of granitic pegmatites in yugoslavia, M. Risti6 and s. Pavlovi6 found in a pegmatite from prokuplje area, Serbia, zircon crystals associated w...

Thermoluminescence (TL) studies of insulators, including crystals of minerals such as calcite, quartz or zircon, have resulted in the development of a wider range of applications in the fields of radiation dosimetry and archaeological and geological dating. Most conventional TL measurements are made by recording light emission during heating by means of broad-band optical filters and blue-sensi...

The oldest-known air-breathing land animal is the millipede Pneumodesmus newmani, found in the Cowie Harbour Fish Bed at Stonehaven, Scotland. Here we report the youngest, most concordant 238U-206Pb zircon age from ash below the fish bed of 413.7±4.4 Ma (±2σ), whereas the youngest age from a tuffaceous sandstone above the fish bed is statistically indistinguishable at 414.3±7.1 Ma. The Cowie Ha...

Detrital zircon geochronology is rapidly evolving into a very powerful tool for determining the provenance and maximum depositional age of clastic strata. This rapid evolution is being driven by the increased availability of ion probes and laser ablation ICP mass spectrometers, which are able to generate age determinations rapidly, at moderate to low cost, and of sufficient accuracy for most ap...

Four metasedimentary zircon populations from different tectonometamorphic units of the Central and the Northern Schwarzwald (Variscan belt, SWGermany) were investigated using SEM, cathodoluminescence and SHRIMP dating. Despite partially strong modifications of primary internal morphologies during Variscan metamorphism at amphibolite (750 C, 0.4– 0.6 GPa) and granulite-facies conditions (950–1,0...

Ancient zircons from Western Australia's Jack Hills preserve a record of conditions that prevailed on Earth not long after its formation. Widely considered to have been a uniquely violent period geodynamically, the Hadean Eon [4.5 to 4.0 billion years ago (Ga)] has recently been interpreted by some as far more benign-possibly even characterized by oceans like those of the present day. Knowledge...