It has long been known that the tension of CO, in arterial blood is approximately the same as that of the alveolar air. Thus, by obtaining samples of alveolar air, one can readily calculate the CO2 tension in the blood and, by usinig Bohr's coefficient, arrive at the figure for the free CO, content (H2CO ,). The total CO2 contenlt less this figure will then represent the combined CO2 (BHCO3) of...

The effect of -Al2O3 particles on the electrochemical codeposition behaviour of Co–Ni alloys from sulfamate electrolyte was investigated by codeposition experiments, zeta potential and electrochemical methods. The results indicate that the presence of Al2O3 particles in Co–Ni sulfamate electrolytes contributes to the preferential codeposition of Co. Moreover, increasing Co2+ concentration also ...

Lipid bilayers and biological membranes are freely permeable to CO(2), and yet partial CO(2) pressure in the urine is 3-4-fold higher than in blood. We hypothesized that the responsible permeability barrier to CO(2) resides in the umbrella cell apical membrane of the bladder with its dense array of uroplakin complexes. We found that disrupting the uroplakin layer of the urothelium resulted in w...

In situ and in vivo experiments were performed on rainbow trout (Oncorhynchus mykiss) to examine (i) the direct effect of CO(2) on the systemic vasculature and (ii) the influence of internal versus external hypercapnic acidosis on cardiovascular variables including blood pressure, cardiac output and systemic vascular resistance. Results from in situ saline-perfused trunk preparations indicated ...

Systematic density-functional calculations have been performed to address an important issue for CO oxidation on redox ceria: the role of lattice oxygen. One major findings is that CO easily grasps one lattice oxygen atom to form CO2 and CO2 on CeO2 (111) and Ce0.75Zr0.25O2 (111) with small activation energies. Zr dopants facilitate the reduction of Ce to Ce and hence weaken the Ce–O bonds, whi...

Soybean (Glycine max L. Merr. cv. Bragg), peanut (Arachis hypogaea L. cv. Georgia Green) and rice (Oryza saliva L. cv. IR-72) were grown for a full season in sunlit, controlled-environment chambers at 350 (ambient) and 700 (double-ambient, elevated) imol CO2 moF' air, and under daytime maximum/nighttime minimum air temperature regimes ranging from 28/18 to 48/38°C for soybean and peanut, or soi...

In Escherichia coli, succinic acid is synthesized by CO2 fixation-based carboxylation of C3 metabolites. A two-step process is involved in CO2 integration: CO2 uptake into the cell and CO2 fixation by carboxylation enzymes. The phosphoenolpyruvate (PEP) carboxylase (PPC) and carboxykinase (PCK) are two important carboxylation enzymes within the succinate synthetic pathway, while SbtA and BicA a...

Imidazolium ion-terminated self-assembled monolayer (SAM)-modified electrodes achieve CO2 conversion while suppressing hydrogen evolution. Immobile imidazolium ion on gold (Au) electrodes reduce CO2 at low overpotential. The distance between electrode and imidazolium ion separated by alkane thiol affects CO2 reduction activity. CO2 reduction current depends on the tunnel current rate. Although ...

The development of a fast and novel methodology to generate carbon-11 carbon monoxide ([11 C]CO) from cyclotron-produced carbon-11 carbon dioxide ([11 C]CO2 ) mediated by a fluoride-activated disilane species is described. This methodology allows up to 74 % conversion of [11 C]CO2 to [11 C]CO using commercially available reagents, readily available laboratory equipment and mild reaction conditi...