The asymmetric unit of the title compound, [Fe(C(12)H(6)O(4))(C(10)H(8)N(2))], consists of two independent Fe(II) atoms, two naphthalene-1,4-dicarboxyl-ate anions and two 4,4'-bipyridine ligands. The Fe(II) atoms are each coordinated by four O atoms of the naphthalene-1,4-dicarboxyl-ate anions and two N atoms of the 4,4'-bipyridine ligands within a distorted octa-hedron. Two Fe(II) atoms are br...

The reaction of [bis{3-methyl-6-(trimethylsilyl)phosphinine-2-yl}dimethylsilane] (19) with one and two equivalents [AuCl(tht)] was attempted in order to selectively form the mono digold species, respectively. species [(AuCl)2(19)] (21) synthesized 32% yield comprehensibly characterized (multinuclear NMR spectroscopy, elemental analysis, mass spectrometry single-crystal X-ray diffraction). monog...

Amphiphilic ligands 4,4'-bis(1-adamantyl-aminocarbonyl)-2,2'-bipyridine (L(1)), 4,4'-bis[5-[N-[2-(3beta-cholest-5-en-3-ylcarbamate-N-yl)ethyl]aminocarbonyl]]-2,2'-bipyridine (L(2)), 4,4'-bis[5-[N-[2-(3beta-cholest-5-en-3-ylcarbamate-N-yl)propyl]aminocarbonyl]]-2,2'-bipyridine (L(3)), and 4,4'-bis(dodecan-12-ol)-2,2'-bipyridine (L(4)) and their heteroleptic ruthenium(II) complexes of the type [R...

The mol-ecule of the title compound, C(7)H(6)ClNO(2), is almost planar, with a dihedral angle of 3.34 (14)° between the COOMe group and the aromatic ring. In the crystal, the mol-ecules are arranged into (1[Formula: see text]2) layers by C-H⋯N hydrogen bonds and there are π-π stacking inter-actions between the aromatic rings in adjacent layers [centroid-centroid distance 3.8721 (4) Å].

THE TITLE SESQUITERPENE [SYSTEMATIC NAME: 6-methoxy-10-methyl-7-(propan-2-yl)-2-oxatricyclo[6.3.1.0(4,12)]dodeca-1(11),4,6,8(12),9-pentaen-5-ol], C(16)H(18)O(3), was isolated from pathogen-infected stele tissue of Gossypium barbadense. There are two mol-ecules in the asymmetric unit and the dihedral angle between their naphtho-furan systems is 86.48 (2)°. In the crystal, O-H⋯O hydrogen bonds be...

In the title compound, catena-poly[bis[(2,2'-bipyridine-κ(2)N,N')(1,1,3,3-tetracyano-2-ethoxypropenido-κN)copper(II)]-μ4-hexanedioato-κ(6)O(1),O(1'):O(1):O(6),O(6'):O(6)], [Cu2(C9H5N4O)2(C6H8O4)(C10H8N2)2]n, the adipate (hexanedioate) dianion lies across a centre of inversion in the space group P1. The Cu(II) centre adopts a distorted form of axially elongated (4+2) coordination, and the Cu(II)...

The mol-ecules of the title compound, C(22)H(17)N, are linked by weak inter-actions, among which the most prominent are C-H⋯π inter-actions. The dihedral angles between the phenyl rings and the quinoline ring system are 43.3 (3) and 21.4 (3)°. The title product resulted from a three-component reaction of benzaldehyde, 1-ethynylbenzene and p-toluidine via C-H activation of 1-ethynylbenzene catal...

The title compound, C(21)H(22)N(2)O(4), was prepared by reaction of 6-methyl-pyrimidine-2,4(1H,3H)-dione and 1-chloro-methyl-4-meth-oxy-benzene. In the title mol-ecule, the central pyrimidine ring forms dihedral angles of 62.16 (4) and 69.77 (3)° with the two benzene rings. In the crystal, weak inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into chains.