نتایج جستجو برای: absolute configuration

تعداد نتایج: 212221  

Journal: :Chemistry 2021

Knowledge about the absolute configuration of small bioactive organic molecules is essential in pharmaceutical research because enantiomers can exhibit considerably different effects on living organisms. X-ray crystallography enables chemists to determine an enantiopure compound due anomalous dispersion. Here, we present determination flavoring agent (+)-γ-decalactone, which liquid under ambien...

2015
Andrea Stierle Donald Stierle Daniel Decato

The crystal structure of the title compound, berkeleydione [systematic name; (5aS,7R,9S,11R,11aS)-methyl 9-hy-droxy-1,1,5,7,9,11a-hexa-methyl-14-methyl-idene-3,8,10-trioxo-1,3,4,5a,6,7,8,9,10,11,11a,12-dodeca-hydro-7,11-methano-cycloocta-[4,5]cyclo-hepta-[1,2-c]pyran-11-carboxyl-ate], C26H32O7, has been reported previously [Stierle et al. (2004 ▶). Org. Lett. 6, 1049-1052]. However, the absolut...

2012
Omar E. Christian Frank R. Fronczek Khoa Ky Shreedu Pradhan Anjela Manandhar Cecilia Richmond

The absolute configuration of 3-benzoyl-4-hy-droxy-6,6-dimethyl-1,5,7-tris-(3-methyl-but-2-en-yl)bicyclo-[3.3.1]non-3-ene-2,9-dione, C(33)H(42)O(4), isolated from Hypericum hypericoides, has been determined. The previous study [Xiao et al. (2007 ▶). J. Nat. Prod.70, 1779-1782] gave only the established relative configuration. The three stereogenic centers are now established as 1R, 5R and 7S on...

Journal: :Angewandte Chemie 2013
Michael Müller Claudia M Orben Nina Schützenmeister Manuel Schmidt Andrei Leonov Uwe M Reinscheid Birger Dittrich Christian Griesinger

The controversy over the absolute configuration of (+)-erythro-mefloquine, the less psychosis-causing enantiomer of the anti-malarial drug Lariam, has been resolved by Mosher ester crystallization. The configuration determined previously by physical methods is correct, whereas the configuration determined by three enantioselective syntheses is wrong.

Journal: :Proceedings of the National Academy of Sciences of the United States of America 1971
A S Meyer E Hanzmann R C Murphy

The absolute configuration of the predominant Cecropia hormone, methyl 12,14-dihomojuvenate, has been determined to be methyl (E,E)-(10R,11S)-(+)-10,11-epoxy-7-ethyl-3,11-dimethyl-2, 6-tridecadienoate (I). The less abundant hormone, methyl 12-homojuvenate, can be presumed by analogy to have the corresponding 3,7,11-trimethyldienoate structure (II). The assignment has been established with micro...

2010
Ibrahim Abdul Razak Abdul Wahab Salae Suchada Chantrapromma Chatchanok Karalai Hoong-Kun Fun

THE TITLE COMPOUND [SYSTEMATIC NAME: 7α,12-dihy-droxy-8,12-abietadiene,11,14-dione or (4bS,8aS,10R)-3,10-dihy-droxy-2-isopropyl-4b,8,8-trimethyl-1,4,4b,5,6,7,8,8a,9,10-deca-hydro-phenanthrene-1,4-dione], C(20)H(28)O(4), is an abietane diterpen-oid, which was isolated from the roots of Premna obtusifolia (Verbenaceae). Its crystal structure has been reported previously [Chen et al. (2000 ▶). Jie...

Journal: :iranian journal of pharmaceutical research 0
xuefeng huang zhongshan hospital, xiamen university yun zhao xiamen university xin jin xiamen university

a water soluble polysaccharide, hb-1, with a molecular weight of 23,930, was isolated from radix ranunculi ternati. by hot water extraction, ethanol precipitation, deproteination,ultrafiltration and gel-filtration column chromatography. its sugar composition was determined by glc as glc, ara, and gal in a molar ration of 16.071: 2.722: 1. and the absolute configuration of glc was identified as ...

Journal: :Bulletin of the Chemical Society of Japan 1983

نمودار تعداد نتایج جستجو در هر سال

با کلیک روی نمودار نتایج را به سال انتشار فیلتر کنید