Acibenzolar-S-methyl (ASM) is a novel fungicide applied for crop protection. A renewable silver amalgam film electrode was used for the determination of ASM in pH 3.4 Britton Robinson buffer using square wave adsorptive stripping voltammetry (SWAdSV). The parameters of the method were optimized. The electroanalytical procedure made possible to determine ASM in the concentration range of 5 10 –3...

The redox behavior of spironolactone (SP) drug in Britton-Robinson (BR) buffer of pH 2-11 was investigated by differential pulse cathodic stripping voltammetry (DPCSV) and cyclic voltammetry (CV) at hanging mercury dropping electrode (HMDE). At pH 9-10.5, the DPCSV of SP drug showed two cathodic peaks at -1.15 and -1.38 V at the HMDE vs. Ag/AgCl reference electrode. In the CV, at pH 9-10, the d...

The advent of stripping voltammetry has improved the performance of analytical voltammetry to a considerable extent.1 The enhanced sensitivity and lower detection limits can be achieved in this technique by enrichment of the analyte prior to voltammetric determination. The common enrichment processes include reduction of metal ions through formation of metal films or amalgams, reductive or oxid...

A method for the determination of food additive vanillin was developed by adsorptive stripping voltammetry. Its determination was carried out at the anodically pre-treated boron-doped diamond electrode in aqueous solutions. Using square-wave stripping mode, the compound yielded a well-defined voltammetric response in phosphate buffer, pH 2.5 at +1.14 V (vs. Ag/AgCl) (a pre-concentration step be...