Nanoindentation in conjunction with piezoresponse force microscopy was used to study domain switching and to measure the mechanical properties of individual ferroelectric domains in a tetragonal BaTiO3 single crystal. It was found that nanoindentation has induced local domain switching; the a and c domains of BaTiO3 have different elastic moduli but similar hardness. Nanoindentation modulus map...

Axisymmetric vibration of an infinite Pyrocomposite circular hollow cylinder made of inner and outer pyroelectric layer of 6mm-class bonded together by a Linear Elastic Material with Voids (LEMV) layer is studied. The exact frequency equation is obtained for the traction free surfaces with continuity condition at the interfaces. Numerical results in the form of data and dispersion curves for th...

Axisymmetric vibration of an infinite Pyrocomposite circular hollow cylinder made of inner and outer pyroelectric layer of 6mm-class bonded together by a Linear Elastic Material with Voids (LEMV) layer is studied. The exact frequency equation is obtained for the traction free surfaces with continuity condition at the interfaces. Numerical results in the form of data and dispersion curves for th...

A new phase boundary is revealed in (1-x)(Bi1/2Na1/2)TiO3xBaTiO3, the most extensively studied leadfree piezoelectric solid solution. This discovery results from a novel method of electron diffraction analysis, which allows for the precise determination of oxygen octahedra tilting in multi-domain perovskite ferroelectrics. The study using this method supports the recently proposed Cc symmetry ...

We proposed a model to study the resistance degradation behavior of ferroelectric oxides in the presence of ferroelectric spontaneous polarization by combining the phase-field model of ferroelectric domains and nonlinear diffusion equations for ionic/electronic transport. We took into account the nonperiodic boundary conditions for solving the electrochemical transport equations and Ginzburg–La...

We report the structural and magnetoelectrical properties of La0.7Ca0.3MnO3/BaTiO3 perovskite superlattices grown on (001)-oriented SrTiO3 by the pulsed laser deposition technique. Magnetic hysteresis loops together with temperature dependent magnetic properties exhibit well-defined coercivity and magnetic transition temperature (TC) ̃140 K. DC electrical studies of films show that the magnetor...

We report on linear and nonlinear dielectric property measurements of BaTiO3–CoFe2O4 (BTO–CFO) ferroelectromagnetic nanocomposites and pure BaTiO3 and CoFe2O4 samples with scanning near-field microwave microscopy. The permitivity scanning image with spatial resolution on the micrometer scale shows that the nanocomposites have a very uniform quality with an effective dielectric constant r 140 ± ...

We have developed a luminescent marker using the second harmonic generation (SHG) from noncentrosymmetric BaTiO3 nanocrystals. These nanoparticles are attractive due to their stable, non-saturating and coherent signal with a femtosecond-scale response time and broad flexibility in the choice of excitation wavelength. In this paper, we report the SHG response of BaTiO3 nanocrystals under a circu...

Freestanding BaTiO3 nanodots exhibit domain structures characterized by distinct quadrants of ferroelastic 90° domains in transmission electron microscopy (TEM) observations. These differ significantly from flux-closure domain patterns in the same systems imaged by piezoresponse force microscopy. Based upon a series of phase field simulations of BaTiO3 nanodots, we suggest that the TEM patterns...