Interest in bimetallic catalysts has risen steadily over the years because of the commercial success of these systems [1]. This success results from an enhanced ability to control the catalytic activity and selectivity by tailoring the catalyst composition [2,3]. A long-standing question regarding such bimetallic systems is the nature of the properties of the mixed metal system which give rise ...

Bimetallic Au-Pd nanoparticles (NPs) were successfully immobilized in the metal-organic frameworks (MOFs) MIL-101 and ethylenediamine (ED)-grafted MIL-101 (ED-MIL-101) using a simple liquid impregnation method. The resulting composites, Au-Pd/MIL-101 and Au-Pd/ED-MIL-101, represent the first highly active MOF-immobilized metal catalysts for the complete conversion of formic acid to high-quality...

in this study, as for the re-casting, surface alloying and re-solidification layer of this alloys at the work piece level machining with wire electro discharge machining (wedm), changes of surface micro hardness with changes of operational parameters has been studied. therefore, study shows using surface alloying phenomena with the diffusion of wire material into the machined surface and select...

A simple method to grow vertically aligned arrays of various forms of single-walled carbon nanotubes (V-SWNT) is reported. CO disproportionation on CoAMo bimetallic catalysts has been used in the synthesis. Resonant Raman and transmission electron microscope (TEM) were employed to characterize the as-produced SWNTs, which display a high purity and very low concentration of other carbon forms. C...

Bimetallic nitrides are now being considered as one of the emerging advanced functional materials due to their characteristic features and remarkable physicochemical properties. Herein, we report a new crystalline bimetallic nitride (Co3ZnN) that belongs to the cubic crystal phase, which was successfully synthesized through direct nitridation of metallic salts as precursors. Co3ZnN nanoparticle...

in this paper, the direct extrusion process of bimetallic rods in conical dies is analyzed by an improved upper bound method. the deformation zone is subdivided into six smaller zones and by considering a non-spherical entrance boundary to the deformation zone, a velocity field is presented which is different from velocity fields employed in previous studies. the total power consumption of the ...

Control of structure and morphology of Pt-based nanomaterials is of great importance for electrochemical energy conversions. In this work, we report an efficient one-step synthesis of bimetallic porous AuPt nanoparticles (PAuPt NPs) in an aqueous solution. The proposed synthesis is performed by a simple stirring treatment of an aqueous reactive mixture including K2PtCl4, HAuCl4, Pluronic F127 a...

We demonstrate resonant Faraday polarization rotation in plasmonic arrays of bimetallic nanoring resonators consisting of Au and Ni sections. This metamaterial design allows to optimize the trade-off between the enhancement of magneto-optical effects and plasmonic dissipation. Nickel sections corresponding to as little as ∼ 6% of the total surface of the metamaterial result in magneto-optically...

Bimetallic oxalates are a class of layered organic magnets with transition metals M(II) and M'(III) coupled by oxalate molecules in an open honeycomb structure. Energy, structure, and symmetry considerations are used to construct a reduced Hamiltonian, including exchange and spin-orbit interactions, that explains the giant negative magnetization in some of the ferrimagnetic Fe(II)Fe(III) compou...

objective: corrosion resistance is among the most important properties of metal alloys used in the oral cavity. consumption of acidic foods reduces the salivary ph and intensifies the corrosion of brackets and orthodontic wires. this study aimed to compare electro galvanic corrosion of different orthodontic brackets and wires and determine the amount of ions released into acidic artificial sali...