The influence of polymeric dispersants containing different functional groups on TiO2 pigment particle suspension was investigated at pH 6.0 and 9.5, using rheology and particle size data. The dispersants chosen were polyacrylic acid and modified polyacrylamides including homo and copolymers modified with carboxylate and/or hydroxyl groups. The pigment suspension was strongly affected by both p...

Utilisation of fatty acids generally relies on pre-existing functional groups such as the carboxylate group or C=C-double bonds. Addition new functionalities into hydrocarbon part opens up possibilities for acid valorisation. In this contribution we demonstrate synthetic potential a peroxygenase mutant AaeUPO-Fett selective oxyfunctionalisation. The w-1 hydroxy (esters) produced are further tra...

α-Carboxylate radical anions are potential reactive intermediates in the free radical oxidation of biological molecules (e.g., fatty acids, peptides and proteins). We have synthesised well-defined α-carboxylate radical anions in the gas phase by UV laser photolysis of halogenated precursors in an ion-trap mass spectrometer. Reactions of isolated acetate (˙CH(2)CO(2)(-)) and 1-carboxylatobutyl (...

A combination of neutron diffraction augmented with isotopic substitution and computer modeling using empirical potential structure refinement has been used to extract detailed structural information for L-glutamic acid dissolved in 2 M NaOH solution. This work shows that the tetrahedral hydrogen bonding network in water is severely disrupted by the addition of glutamic acid and NaOH, with the ...

[Cu(C16H18N3O2)]Br.CH4O, Mr = 459.83, orthorhombic, P2(1)2(1)2(1), a = 10.452 (4), b = 12.197 (7), c = 14.984 (6) A, V = 1910 (3) A3, Z = 4, Dm = 1.61 (1), Dx = 1.599 g cm-3, lambda(Mo K alpha) = 0.71073 A, mu = 32.37 cm-1, F(000) = 932, T = 174 K, R = 0.0396, wR = 0.0419, 1146 observed reflections [I greater than 3 sigma(I)]. The title compound is a polymeric species in the solid state, with a...

Synthesis of imidazolium carboxylate compounds was efficiently achieved by electrochemical reduction of imidazolium precursors under very mild conditions.

The development of models that predict membrane performance has contributed a better understanding of the basic principles and mechanisms of solute rejection and deposition. It also serves as fundamental properties that allow specific characterization determination. This work fabricates hollow fiber membranes using Polyethersulfone (PES). The membranes were fabricated in-house using phase inver...

1. An organism was isolated by enrichment culture that was capable of using thiophen-2-carboxylate as sole source of carbon, energy and sulphur for growth. 2. Analysis of the cellular protein after growth of the organism on thiophen-2-[(14)C]carboxylate showed that only glutamate, proline and arginine were labelled. All the radioactivity in the glutamate was confined to C-1. 3. In the presence ...