Activation of the moderate carcinogen 6-methylbenzo[a]pyrene (6-CH(3)BP) by one-electron oxidation to form DNA adducts was studied. Iodine oxidation of 6-CH(3)BP in the presence of dGuo produces BP-6-CH(2)-N(2)dGuo, BP-6-CH(2)-N7Gua and a mixture of 6-CH(3)BP-(1&3)-N7Gua, whereas in the presence of Ade the adducts BP-6-CH(2)-N1Ade, BP-6-CH(2)-N3Ade, BP-6-CH(2)-N7Ade and 6-CH(3)BP-(1&3)-N1Ade ar...

The Me₂Si-bridged ansa-Cp/amido half-metallocene, [Me₂Si(η⁵-Me₄C₅)(NtBu)]TiCl₂, termed a "constrained-geometry catalyst (CGC)", is a representative homogeneous Ziegler catalyst. CGC derivatives with the [1,2]azasilinane framework, in which the amide alkyl substituent is joined by the Si-bridge, were prepared, and the catalytic performances of these species was studied. Me₄C₅HSi(Me)(CH₂CH=CH₂)-N...

The chemical syntheses of two new, completely nonhydrolyzable phosphinate analogues of lecithin are described. These have the structures ROCH(2)CH(OR)CH(2)CH(2)P(O)(O(-))CH(2)CH(2)N(+)(CH(3))(3) and ROCH(2)CH(OR')CH(2)P(O)(O(-))CH(2)CH(2)CH(2)N(+)(CH(3))(3), where R = C(18)H(37) and R' = C(16)H(33); each is thus isosteric with lecithin on either side of the phosphorus function. The infrared spe...

Cold stress is an ‎important limiting factor for cereal production. Barley is a host species for arbuscular mycorrhizal fungi (AMF) with a high genetic diversity in response to cold stress. In order to explore the mechanisms for the ameliorative effect of AMF under cold stress, an experiment was undertaken using completely randomized block design with three factors including temperature treatme...

The present study examined the effects of chitosan (Ch) and chitosan combined with sodium tripolyphosphate (Nch) nanoparticles as coating materials for Cynoglossus arel fillets during superchilling storage. Treatments included the following: C (untreated, control samples), AC (treated with 1% glacial acetic acid, acid control), Ch (treated with 2% w/v chitosan solution, Chitosan) and Nch (treat...