Fe isotopes have been applied to the petrogenesis of ore deposits. However, behavior iron in mineralization porphyry-skarn deposits is still poorly understood. In this study, we report mineral separations (magnetite, pyrite, chalcopyrite and pyrrhotite) from two different skarn deposits, i.e., Tonglvshan Cu-Fe deposit developed an oxidized hydrothermal system Anqing Cu a reduced system. both ca...