Pollution of water bodies by phosphorus in runoff from soil amended with animal manures is one of the greatest threats to water quality in developed countries. The environmental fate of manure phosphorus is determined in part by its chemical composition, yet extraction procedures to assess this are poorly developed and provide no structural information. We used solution 31P NMR spectroscopy to ...

As an emerging two-dimensional material, black phosphorus (BP) has fascinating structure and electronic properties, affording broad applications in field-effect transistors, optoelectronic devices, energy biomedicines. However, the lone pair electrons of atoms readily react with oxygen, so few-layer BP is easily oxidized degraded when exposed to air. Therefore, ambient stability needs be enhanc...

Despite the abundant evidence for the enrichment of phosphorus during the petrogenesis of natural ferro-basalts, the effect of phosphorus on the physical properties of these melts is poorly understood. The effects of phosphorus on the viscosity, density and redox ratio of a ferro-basaltic melt have been determined experimentally. The viscosity measurements were obtained using the concentric cyl...

Room temperature sodium-ion batteries are of great interest for high-energy-density energy storage systems because of low-cost and natural abundance of sodium. Here, we report a novel phosphorus/graphene nanosheet hybrid as a high performance anode for sodium-ion batteries through facile ball milling of red phosphorus and graphene stacks. The graphene stacks are mechanically exfoliated to nanos...

As we begin to understand the origin and evolution of life on Earth and investigate the possibility of extraterrestrial life, the need to scientifically approach fundamental questions such as ‘What is Life ?’ increases. In beginning to answer such questions we can look at the ingredients of life on Earth. Here we present an overview of our understanding of the composition of life on Earth. At t...

In addition to the 5'-phosphate ester on its flavin mononucleotide (FMN) moiety, flavodoxin from Azotobacter vinelandii contains 2 moles of tightly bound phosphate. One non-coenzyme phosphate group is covalently bound to the protein, as it remains with the protein on acid precipitation, whereas the other phosphate is released. The invariance of the (31)P nuclear magnetic resonance chemical shif...

The effectiveness of chemical amendment of pig slurry to ameliorate phosphorus (P) losses in runoff is well studied, but research mainly has concentrated only on the runoff pathway. The aims of this study were to investigate changes to leachate nutrient losses, soil properties and greenhouse gas (GHG) emissions due to the chemical amendment of pig slurry spread at 19 kg total phosphorus (TP), 9...

A new fertilizer technology developed at Penn State University offers several potential benefits for turfgrass cultivation. The new technology employs a phosphorus buffering system (PBS), which , maintains a steady phosphorus concentration in the soil solution over time. The PBS has the size and consistency of sand (Fig. 1) and can be mixed with any soil media. Once charged with phosphorus, the...

in this research, several chemical extractants and modified olsen methods were studied in 25 surface-calcareous soils (0-30 cm) for determining available phosphorus (p) for corn (zea mays l.) plant. in this experiment, the highest correlation was obtained between extracted p by olsen and colwell methods (nahco3-extractable p) and dry weight of corn shoot (r =0.67 and 0.75, p