A combination of experimental, molecular dynamics, and kinetics modeling studies is applied to a system of concentrated aqueous sodium chloride particles suspended in air at room temperature with ozone, irradiated at 254 nanometers to generate hydroxyl radicals. Measurements of the observed gaseous molecular chlorine product are explainable only if reactions at the air-water interface are domin...

A rapid and simple sequential potentiometric method is described for the determination of nitrate and chloride ions in vegetables, by using home-made ion selective electrodes. The extraction of both ions from the vegetable samples was effected by magnetic stirring of the samples during 30 min in water at room temperature. Direct Potentiometry was used as analytical technique for measurement. Th...

The potentials of mean force between sodium and chloride ions and between sodium and dimethylphosphate ions in aqueous solution are calculated by the probability ratio method using adaptive umbrella sampling Monte Carlo with a variety of simulation setups. The potential of mean force of sodium chloride is found to have only one minimum in contradiction to earlier molecular dynamics results with...

Distal nephron function of the rat during lithium chloride infusion. Chronic lithium (Li) administration in the rat leads to reduced renal concentration (TCH20) without alterations in renal dilution (CH), To examine the acute effects of lithium on TH2O and C1120, rats were infused with a solution composed of 1% sodium chloride and 1% lithium chloride or a 0.225% lithium chloride solution at rat...

The transport of ions across the membranes of cells and organelles is a prerequisite for many of life's processes. Transport often involves very precise selectivity for specific ions. Recently, atomic-resolution structures have been determined for channels or pumps that are selective for sodium, potassium, calcium, and chloride: four of the most abundant ions in biology. From these structures w...

In excitable cells, the generation of an action potential (AP) is associated with transient changes of the intra- and extracellular concentrations of small ions such as Na(+), K(+) and Cl(-). If these changes cannot be fully reversed between successive APs cumulative changes of trans-membrane ion gradients will occur, impinging on the cell volume and the duration, amplitude and frequency of APs...

Studies of the sodium, chloride and water balance of Xiphister atropurpureus (Evans, 1967 a-c) showed that this intertidal teleost is relatively impermeable to these ions and to water, has an exchange-diffusion system for sodium only, and apparently lowers its permeability to sodium but not to chloride or water when acclimated to a lower salinity. An investigation of the intertidal teleost, Pho...

A synthetic receptor, with an ability to bind sodium or potassium chloride as a contact ion-pair, is shown to effectively transport either salt across vesicle membranes. Significant transport is observed even when the transporter: phospholipid ratio is as low as 1:2500. Chloride efflux from unilamellar vesicles is monitored using a chloride selective electrode. Mechanistic studies indicate that...

One type of all-solid-state chloride sensor was fabricated using a MnO(2) electrode and a Ag/AgCl electrode. The potentiometric response of the sensor to chloride in synthetic concrete pore solutions was systematically studied, and the polarization performance was also evaluated. The results show a good linear relationship between the potential reading of the sensor and the logarithm of chlorid...

The dynamics of water and chloride counter ions (Cl) in single unit cells of orthorhombic and tetragonal hen egg white lysozyme lattices are investigated by 5 ns molecular dynamics simulations. The electrostatic interaction inside the crystal channel significantly influences the diffusion of chloride ions. The corresponding diffusion constants of Cl calculated by averaging over all ions during ...