The cation, anion, and solvent in the title compound, [K(C(18)H(36)N(2)O(6))][Co(C(8)H(12))(C(16)H(10))(2)]·0.5C(5)H(12), are well separated. The pentane solvent mol-ecules are found in channels along [100] and were modeled as disordered over crystallographic inversion centers. Using the mid-points of the coordinated olefins, the angle between the C(py)/C(py)-Co-C(py)/C(py) and the C(cod)/C(cod...

Parkinson's disease (PD) is a common neurodegenerative condition in which abnormalities in protein homeostasis, or proteostasis, may lead to accumulation of the protein α-synuclein (α-syn). Mutations within or multiplications of the gene encoding α-syn are known to cause genetic forms of PD and polymorphisms in the gene are recently established risk factors for idiopathic PD. α-syn is a major c...

The dynamics of retained and deactivating species in a SAPO-18 catalyst during the methanol-to-olefins reaction have been followed using combination ex-situ in-situ techniques differential integral reactors.The were analyzed extraction, FTIR UV-vis spectroscopies combined with online product analysis (gas chromatography mass spectrometry). composition extracted soluble was determined gas chroma...

Cell fate in multicellular organism is regulated by the diffusible factor from surrounding cells in concentration-dependent manner. TGF-beta is a large protein family of the diffusible proteins secreted from a localized source. The signal of TGF-beta is transduced by Smad family transcription factor. Though it is well known that the stoichiometry of Smads in the transcriptional complex regulate...

ti-mcm-41 was synthesized at ph 3, 7 and 11. the titanium content was determined by aas and found to be 4%, 3.2% and 4.5%, respectively. in order to increase the titanium content in ti-mcm-41, ti(iv) ions were grafted onto ti-mcm-41 using ticl4 in toluene and ti(obu)4 in ethanol. the incorporation of ti was determined to be 28% and 30%, respectively. the oxidation of olefins such as cyclopenten...

In order to develop new, efficient and environmentally friendly methods for the preparation of practically valuable esters carboxylic acids, studies hydroalkoxycarbonylation reaction a number terminal olefins normal structure (hexene-1, heptene-1, octene-1, nonene-1) with carbon monoxide alcohols in presence metal complex catalysts based on palladium phosphine complexes at low pressures (≤ 20 a...

Ti-MCM-41 was synthesized at pH 3, 7 and 11. The titanium content was determined by AAS and found to be 4%, 3.2% and 4.5%, respectively. In order to increase the titanium content in Ti-MCM-41, Ti(IV) ions were grafted onto Ti-MCM-41 using TiCl4 in toluene and Ti(OBu)4 in ethanol. The incorporation of Ti was determined to be 28% and 30%, respectively. The oxidation of olefins such as cyclopenten...