The separation, capture, and storage of CO2 , the major greenhouse gas, from industrial gas streams has received considerable attention in recent years because of concerns about environmental effects of increasing CO2 concentration in the atmosphere. An emerging area of research utilizes reversible CO2 sorbents to increase conversion and rate of forward reactions for equilibrium-controlled reac...

CO2 capture and storage (CCS) is widely regarded as a key technology for reducing greenhouse gas emissions from large industrial point sources. It entails the capture of a relatively pure CO2 from exhaust gases using different techniques, and then storing this captured gas in various geological sinks. Large-scale deployment of CCS requires the comprehensive evaluation of candidate sources and s...

Carbon dioxide capture and storage (CCS) links together technologies that separate carbon dioxide (CO2) from fixed point source emissions and transport it by pipeline to geologic reservoirs into which it is injected underground for long-term containment. Previously, models have been developed to minimize the cost of a CCS infrastructure network that captures a given amount of CO2. The CCS proce...

We present the in silico design of a MOF-74 analogue, hereon known as M2(DHFUMA) [M = Mg, Fe, Co, Ni, Zn], with enhanced small-molecule adsorption properties over the original M2(DOBDC) series. Constructed from 2,3-dihydroxyfumarate (DHFUMA), an aliphatic ligand which is smaller than the aromatic 2,5-dioxidobenzene-1,4-dicarboxylate (DOBDC), the M2(DHFUMA) framework has a reduced channel diamet...

Direct air carbon capture and storage (DACCS) involves a set of approaches for capturing CO2 directly from the its subsequent long-term storage. DACCS is at an early stage...

As part of DOE/NETL’s Carbon Sequestration Program, we are developing an integrated, multi-pollutant modeling framework to evaluate the costs and performance of alternative carbon capture and sequestration technologies for fossil-fueled power plants. The model calculates emissions, costs, and efficiency on a systematic basis at the level of an individual plant or facility. Both new and existing...

avoidance cost of carbon capture from pulverized coal plants. To investigate this possibility, a technoeconomic oxyfuel model was constructed. The model was exercised to explore the effect on CO2 avoidance cost and LCOE from several key parameters, namely: CO2 purity, oxidant purity, CPU and ASU performance and cost, coal composition, and geographic location. Monte-Carlo techniques were then us...