Multi-photon ionization (MPI) of the RNA base uracil has been studied in the wavelength range 220-270 nm, coinciding with excitation to the S2(ππ*) state. A fragment ion at m/z = 84 was produced by 2-photon absorption at wavelengths ≤232 nm and assigned to C3H4N2O(+) following CO abstraction. This ion has not been observed in alternative dissociative ionization processes (notably electron impac...

Computational studies on the photochemistry of the open-shell chromium oxalate [Cr(C(2)O(4))(3)](3-) ion, including its non-adiabatic relaxation pathways, have been performed. The presence of the peaked conical intersection of a quasi-Jahn-Teller type, connecting the (4)T state with (4)A(2) ground state, accounts for the observed photoinduced racemization. This involves the rupture of one of th...

We apply a combination of state-of-the-art experimental and quantum-chemical methods to elucidate the electronic and chemical energetics of hydrogen adduction to a model open-shell graphene fragment. The lowest-energy adduct, 1H-phenalene, is determined to have a bond dissociation energy of 258.1 kJ mol-1, while other isomers exhibit reduced or in some cases negative bond dissociation energies,...

A finite element analysis is presented for sloshing and impulsive motion of liquid-filled conical tanks during lateral anti-symmetric excitation. The performed analyses led to the development of a number of charts which can be used to identify the natural frequency, the mode shapes of conical tanks for both fundamental and the cos(θ)-modes of vibration. Conical tank geometry was described with ...

In this article, a semi-analytical solution is provided to investigate the free vibration characteristics of rotating truncated conical shells surrounded by Winkler–Pasternak type foundation. It assumed that material shell composed epoxy as matrix and graphene nanoplatelets (GPLs) reinforcement dispersed in both thickness length directions shell. The modeled based on first-order shear deformati...

The physiological functions of epidermal cells are largely determined by their diverse morphologies. Most flowering plants have special conical-shaped petal epidermal cells that are thought to influence light capture and reflectance, and provide pollinator grips, but the molecular mechanisms controlling conical cell shape remain largely unknown. Here, we developed a live-confocal imaging approa...

Optical and radio afterglows arising from the shocks by relativistic conical ejecta running into pre-burst massive stellar winds are revisited. Under the homogeneous thin-shell approximation and a realistic treatment for the lateral expansion of jets, our results show that a notable break exists in the optical light curve in most cases we calculated in which the physical parameters are varied w...

Conical queries are a novel type of query with an increasing number of applications. Traditional index structures and retrieval mechanisms, in general, have been optimized for rectangular and circular queries, rather than conical queries. In this paper, we focus on conical queries which can be deened as a multi-dimensional cone in a multi-dimensional data space. We develop a model for expressin...