Reactions of the preformed cluster [(η(5)-C(5)Me(5))(2)Mo(2)(μ(3)-S)(4)Cu(2)(MeCN)(2)](ClO(4))(2) (1) with two tetraphosphine ligands, 1,4-N,N,N',N'-tetra(diphenylphosphanylmethyl)benzene diamine (dpppda) and N,N,N',N'-tetra(diphenylphosphanylmethyl)ethylene diamine (dppeda), produced two bicyclic clusters {[(η(5)-C(5)Me(5))(2)Mo(2)(μ(3)-S)(4)Cu(2)](2)(L)}(ClO(4))(4) (3: L = dpppda; 4: L = dppe...

We study Ni 80 Fe 20-based permalloys with the relativistic spin-polarized Korringa-Kohn-Rostoker electronic structure method. Treating the compositional disorder with the coherent potential approximation, we investigate how the magnetocrys-talline anisotropy, K, and magnetostriction, λ, of Ni-rich Ni-Fe alloys vary with the addition of small amounts of non-magnetic transition metals, Cu and Mo...

The resistive switching characteristics of the Cu/SiO x /Pt structure (control sample) exhibited a direct correlation to humidity. The H2O vapor formed the Cu oxide at the Cu/SiO x interface, and Cu ions were injected from the Cu oxide into the SiO x layer, thus improving the resistive switching. However, the control sample demonstrated substantial switching dispersion in a vaporless environmen...

Molybdenum (Mo) content of water treatment residuals (WTRs) was determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES) to evaluate suitability for land application under state regulatory policies that limit Mo to 18 mg kg-1. Samples of WTR were collected from 32 Pennsylvania facilities that employ aluminum salts, ferric chloride, and/or polymers for coagulation. The mea...

Excellent resistive switching memory characteristics were demonstrated for an Al/Cu/Ti/TaOx/W structure with a Ti nanolayer at the Cu/TaOx interface under low voltage operation of ± 1.5 V and a range of current compliances (CCs) from 0.1 to 500 μA. Oxygen accumulation at the Ti nanolayer and formation of a defective high-κ TaOx film were confirmed by high-resolution transmission electron micros...

Supergene oxidation-leaching and secondary sulfide enrichment in the SarCheshmeh porphyry Cu-Mo deposit generated a supergene profile to depths of 20 to 80 meters with oxide ore reserve about 22 Mt. @1.08% Cu and sulfides ore [email protected]% Cu. Geochemical distribution and behavior of trace metals associated with Cu namely Mo, Au, and Ag in the supergene profile of the SarCheshmeh were po...

The electronic interactions in Pd/Mo( 1 IO), Pd/Ru(0001), and Cu/Mo( 110) have been examined by means of X-ray photoelectron spectroscopy (XPS). The shifts in core-level binding energies indicate that adatoms in a monolayer of Cu or Pd are electronically perturbed with respect to surface atoms of Cu(100) or Pd(100). By comparison of these results with those previously presented in the literatur...

Thirty-two beef heifers were used to examine the effect of dietary copper depletion and repletion on neutrophil and lymphocyte functions. Heifers allotted to the control group (C+; n = 8) were fed a basal roughage/concentrate diet with Cu-sulfate supplementation (Cu > or = 8 ppm). To induce a Cu deficiency (depletion phase d 0 to 60), treated (T; n = 24) heifers received a diet supplemented wit...