Trends in oxygen reduction activity of Pd/Cu bimetallic random alloy nanoparticles are determined with calculations of oxygen binding for a range of compositions. A reduction in the average oxygen binding is found as Cu is added to Pd, indicating an increase in catalytic activity up to a peak at 1:1 Pd/Cu ratio. Calculations show that Cu reduces the Pd-O binding energy and Pd increases the Cu-O...

A reliable Cu-Cu bonding joint was achieved by using the highly sinterable Cu nanoparticle paste. Pure copper nanoparticles used in the preparation of nanoparticle paste were synthesized through simple routes, with an average size of 60.5 nm. Under an Ar-H2 gas mixture atmosphere, the Cu nanoparticle paste exhibited large areas of fusion after sintering at 300 °C and reached a low electrical re...

In this paper, a novel method of producing bi-metallic alloy nanoparticles at low temperatures using hydrogen bombardment of thin films, deposited on glass substrates, is introduced. Optical and morphological characteristics of the nanoparticles were extensively studied for various conditions of plasma treatment, such as plasma power density, temperature, duration of hydrogen bombardment, thick...

In this paper, a novel method of producing bi-metallic alloy nanoparticles at low temperatures using hydrogen bombardment of thin films, deposited on glass substrates, is introduced. Optical and morphological characteristics of the nanoparticles were extensively studied for various conditions of plasma treatment, such as plasma power density, temperature, duration of hydrogen bombardment, thick...

Numerical investigation of heat transfer over a backward facing step (BFS), using nanofluids is presented. Different volume fractions of nanoparticles are presented in the base fluid besides different type of nanoparticles have been used. The finite volume technique is used to solve the momentum and energy equations. The distribution of Nusselt number at the top and the bottom walls of the BFS ...

The attractive force between the nanoparticles can cause them to aggregate. Therefore, nanoparticles have to be dispersed by different methods, in order to utilize their unique material characteristics completely. This study aims to use the self-developed nanofluids synthesis system to produce a Cu-based nanofluid with good suspension stability and particle dispersion. Parameters such as peak c...

Shape- and size-controlled syntheses of metal nanoparticles have been achieved by galvanic displacement reaction between an aqueous solution of metal salt and Cu foil substrate. In particular, cubic and spheric nanoparticles of Pt (Au) with a fairly narrow size distribution were produced by reacting K(2)PtCl(4) (HAuCl(4)) with a Cu foil in an aqueous medium with and without CuCl(2) under differ...

Nanoscale alloying and phase transformations in physical mixtures of Pd and Cu ultrafine nanoparticles are investigated in real time with in situ synchrotron-based x-ray diffraction complemented by ex situ high-resolution transmission electron microscopy. The combination of metal-support interaction and reactive/non-reactive environment was found to determine the thermal evolution and ultimate ...

Metallic nanoparticles are more and more widely used in an increasing number of applications. Consequently, they are more and more present in the environment, and the risk that they may represent for human health must be evaluated. This requires to increase our knowledge of the cellular responses to nanoparticles. In this context, macrophages appear as an attractive system. They play a major ro...