نتایج جستجو برای: cuii complex
تعداد نتایج: 784079 فیلتر نتایج به سال:
Four new NiII, CoII, ZnII, and CuII complexes with the promising anti-tuberculosis drug (E/Z)-N′-((5-Hydroxy-3,4-bis(hydroxymethyl)-6-methylpyridin-2-yl)methylene)-isonicotino-hydrazide (LH) were synthesized characterized by structural methods: single-crystal X-ray diffraction, vibrational spectroscopy, mass spectrometry. The ZnII metal ions form only amorphous phases various morphologies accor...
Two novel heterotrimetallic octa-[Cu2CoPbCl4(L)4]2 (1) and pentanuclear [Cu2CoCd2Cl6(L)4(HOMe)2] (2) complexes have been prepared in one-pot reactions of zerovalent copper with metal chlorides in a methanol (for 1) or acetonitrile (for 2) solution of 2-(dimethylamino)ethanol (HL) in open air. The crystal structures of both compounds consist of discrete centrosymmetric heterotrimetallic molecule...
New molecular complexes of fullerenes C60 and C70 with tetraphenylporphyrins [M(tpp)] in which M-H2, MnII, CoII, CuII, ZnII and Fe(III)Cl, have been synthesised. Crystal structures of two C60 complexes with H2TPP, which differ only in the number of benzene solvated molecules, and C60 and C70 complexes with [Cu(tpp)] have been studied. The fullerene molecules form a honeycomb motif in H2TPP.2C60...
Reaction of 2,4-pentanedione with thiosemicarbazide in 1:2 ratio produces cyclic pyrazoline thiosemicarbazone (H2L2 L2 = C7H12N6S2). The obtained ligand has been characterized by elemental analysis, UV–Visible, FTIR, 1H and 13C NMR. results suggest that the is pyrazolinic form, finally structure confirmed single crystal X-ray diffraction. [(L2•)Cu(SCN)] copper complex prepared reaction H2L2 thi...
The flavonoid-based macroinitiator was received for the first time by the transesterification reaction of quercetin with 2-bromoisobutyryl bromide. In accordance with the "grafting from" strategy, a naturally-occurring star-like polymer with a polar 3,3',4',5,6-pentahydroxyflavone core and hydrophobic poly(tert-butyl acrylate) (PtBA) side arms was synthesized via a simplified electrochemically ...
Resistance to antimicrobial agents is responsible for major social and economic losses. The World Health Organization estimated 700,000 global deaths a year due resistance. use of layered double hydroxides (LDHs) as antibacterial materials could present way reduce the risk bacterial infections resistance, by partial release metallic ions in aqueous dispersion. dissolution different synthetic LD...
Precatalyst control: [CuII(OTf)2(pyb)2]2 CH3CN (1), in which pyb is 1-(2-pyridyl)benzotriazole, enables the synthesis of a wide range propargylamines by A3 coupling reaction at room temperature absence additives. The hybrid N,N?-bidentate ligand imposes exclusive trans coordination Cu, can rotate and modulate charge distribution flux, thus orchestrating structural electronic precatalyst control...
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