Structures and spectra are calculated for Si(n) and Si(n)-Gly (n = 3-5) complexes. Relative stability differences of Gly conformers are magnified by interactions with the Si(n) cluster, so that one conformer of Si(n)-Gly is stabilized. Significant charge transfer occurs from the amino group in Gly to a Si atom in the cluster. Interactions with Gly are predicted to shift the excitation energies ...

The interaction of carbonic anhydrase (CA) isozymes I and II with a series of As(III) derivatives, dialkyl and diaryl rac-2,3-dimyristoyloxypropyldithioarsonites, was investigated kinetically and spectrophotometrically, utilizing the native and Co(II)-substituted enzymes. Depending on the substitution pattern at the -As(SR)(2) moiety of the investigated derivatives, inactive compounds were foun...

in design of experiments, analysis and identifying those variables that affect the outputs are of interest. response surface methodology is a mathematical-statistical method to optimize the experiment outputs. this method tries to find the best response levels by optimizing the design variables called factors. in many engineering applications, robust design has become the most important issues....

Indonesia has a new seismic code, namely SNI 1726 2019 (SNI 2019). It is developed based on the 2017 Indonesian Earthquake Source, Hazard Maps, and ASCE 7-16. This paper intended to explain procedure for calculating response spectrum according 2019, at ten ports located in Indonesia. The results are then verified with software RSA2019. Furthermore, it will be compared 2012 2012) see difference ...

The electronic spectra of carbon nanotubes and other nanoscale systems are quantized because of their small radii. Similar quantization in the phonon spectra has been difficult to observe because of the far smaller energy scale. We probed this regime by measuring the temperature-dependent specific heat of purified single-wall nanotubes. The data show direct evidence of one-dimensional quantized...