In this study, eight hydrophobic supramolecular (SUPRA) solvents composed of tetrabutylammonium chloride and tetradecyltrimethylammonium bromide as amphiphiles four perfluorinated compounds (hexafluoroisopropanol, trifluoroacetic acid, pentafluoropropionic acid heptafluorobutyric acid) coacervation-inducing agents were developed. The SUPRA phase volumes determined a function individual concentr...

Until recently, sample preparation was carried out using traditional techniques, such as liquid-liquid extraction (LLE), that use large volumes of organic solvents. Solid-phase extraction (SPE) uses much less solvent than LLE, although the volume can still be significant. These preparation methods are expensive, time-consuming and environmentally unfriendly. Recently, a great effort has been ma...

43 Solidified floating organic drop micro-extraction (SFODME) for simultaneous separation/pre-concentration and determination of cadmium by atomic absorption spectroscopy R. Parviz, M. Honari Department of Chemistry, Faculty of Science, Islamic Azad University Shahr-E-Rey Branch, Shahr-E-Rey, Iran Department of Plant Breading and Biotechnology, Agriculture and Natural Resources Faculty, Tehran ...

This work describes the development of an HPLC-FLD methodology for separation five fluoroquinolones (ciprofloxacin, enrofloxacin, sarafloxacin, norfloxacin and levofloxacin) followed by optimization DLLME process clean-up preconcentration enrofloxacin in samples seawater river water. The mobile phase used chromatographic consisted methanol: phosphate buffer (NaHPO4 H2O 0.04 M pH 3 with H3PO4 85...

A simple and rapid microextraction procedure based on dispersive liquid-liquid microextraction (DLLME) coupled with gas chromatography-flame ionization detection (GC-FID) was developed for the extraction and analysis of 2-phenylethanol in rose water sample. In the proposed approach, carbon tetrachloride and ethanol were used as extraction and dispersive solvents, respectively. Some important pa...

Background & Aims: In this study, using a liquid-liquid microextraction method for pre-concentration trace amounts of aflatoxins, the amount of Aflatoxins B1 and B2 in powdered milk was determined. Determination of aflatoxins was done by using high-performance liquid chromatography coupled with fluorescent detector. Method: Samples were extracted by immunoaffinity column (IAC) clean-up, and the...