The cycling performance and SEI composition of Si nano-particle anodes in electrolytes containing 5–25 wt% fluoroethyelene carbonate (FEC) and 3–6 wt% vinylene carbonate (VC) has been investigated by a combination of by electrochemical cycling, electrochemical impedance spectroscopy, IR-ATR and XPS. The incorporation of FEC or VC changes the cycling performance, impedance, electrode morphology,...

Magnesium-ion conducting gel polymer electrolytes (GPEs) based on PMMA with ethylene carbonate (EC) and propylene carbonate (PC) as a plasticizing solvent were prepared via the solution casting technique. Mg(CF3SO3)2 salt was used as source of magnesium ions, Mg 2+ . The variation of conductivity with salt concentrations, from 5 wt.% to 30 wt.% was studied. The gel polymer electrolyte with comp...

Original scientific paper Plasma Electrolytic Oxidation (PEO) of NiTi alloy was studied in the electrolyte consisting generally of concentrated orthophosphoric acid with an addition of copper II nitrate. The PEO process was used to obtain a nanostructured coating on the Nitinol surface. The surface layer analyses methods, such as scanning electron microscopy (SEM) with the energy-dispersive X-r...

This paper reports on Ag-Ge-Se solid electrolyte films which can support the rapid net displacement of metal mass from a silver source to a target location within a MEMS device at low voltage and current. This displacement of mass can be used to alter material parameters and we have demonstrated a tunable MEMS resonator using this principle. In this application, the electrodeposited mass is mad...

Microelectrodes, printed as an array on the surface of a silicon chip, generate chemically active species in a solution of electrolyte held between the electrode array and a glass plate. The active species induce chemical change in molecules coupled to the surface of the glass plate, which is separated from the electrode array by a gap of several micrometers. This paper explores the nature and ...

Graphite is the most used lithium intercalation host for negative electrode of lithium-ion battery. Extensive research has been carried out to achieve high Coulombic Efficiency (CE) and long cycle life graphite anode. Here, LFP/graphite (graphite from Vendor 1) cells that undergo formation at 40 °C with either 1.2 M LiPF 6 dissolved in ethylene carbonate:dimethyl carbonate (EC:DMC), or carbonat...

Ion conducting polymer electrolytes composed of poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP), poly(methyl methacrylate) (PMMA) and lithium triflate (LiTf) were prepared using the solution casting method. Structural change and complex formation in the blend electrolyte systems were confirmed from the X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy and scann...