In polar fluids such as water and methanol, the peak of the solvated electron’s absorption spectrum in the red has been assigned as a sum of transitions between an s-like ground state and three nearly degenerate p-like excited states bound in a quasi-spherical cavity. In contrast, in weakly polar solvents such as tetrahydrofuran (THF), the solvated electron has an absorption spectrum that peaks...

We report the synthesis and characterization of several sizes of Mn-doped ZnO nanocrystals, both in the free-standing and the capped particle forms. The sizes of these nanocrystals could be controlled by capping them with polyvinylpyrollidone under different synthesis conditions and were estimated by X-ray diffraction and transmission electron microscopy. The absorption properties of PVP-capped...

The microstructure, electronic structure and chemical bonding of chromium carbide thin films with different carbon contents have been investigated with high-resolution transmission electron microscopy, electron energy loss spectroscopy and soft x-ray absorption-emission spectroscopies. Most of the films can be described as amorphous nanocomposites with non-crystalline CrC(x) in an amorphous car...

2014 We present (a) a local-orbital formulation of the electron-hole interaction in a heteropolar semiconductor which takes into account both the screened electron-hole attraction and its exchange counterpart, giving rise to the excitonic and local-field effects, respectively, and (b) a calculation of the absorption spectrum in GaP, which demonstrates the dominant rôle played by the continuum-e...

Spinel zinc manganese oxide (ZnMn2O4) nanorods were successfully prepared using the previously synthesized α-MnO2 nanorods by a hydrothermal method as template. The nanorods were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, UV-Vis absorption, X-ray photoelectron spectroscopy, surface photovoltage spectroscopy, and Fourier transform infrared...

We have studied laser absorption, hot electron emission, and the energy spectrum of hot electrons produced during the interaction of a 150 fs, 5 mJ, 800 nm p-polarized laser pulse at 8x10(15) W/cm(2) with metallic and dielectric target materials. Because dielectric targets are much less conductive, the charge separation potential in dielectric targets is higher than that of metallic targets. Th...

A simple waveguide arrangement has been developed for the study of microwave absorption and emission from a magnetized afterglow plasma column. The time and frequency resolved measurements are performed by a sampling radiometer. A comparison and null technique permits the direct measurement of the electron temperature. Continuous plots of the temperature vs frequency, magnetic field, and afterg...

A new approach for enhancing the exciton absorption and increasing the saturation limit in quantum wells (QWs), using tensile strain, is proposed. Because of the valence-band mixing in a strained QW, the in-plane hole mass can become very large or negative. This leads to a heavy electron-hole reduced mass (exciton mass), and therefore to a small exciton radius. Exciton absorption is substantial...

Multi-walled carbon nanotubes (MWCNT)-doped TiO2 thin films were synthesized by the dip-coating method. The obtained products were characterized by SEM, EDX, XRD, and UV-vis absorption spectroscopy. The XRD patterns showed the presence of anatase phase. Absorption spectrum of MWCNT-doped TiO2 revealed a red shift in the optical absorption edge due to carbon doping. The photocatalytic properties...

Although simulations have predicted that the hydrated electron s absorption spectrum is inhomogeneously broadened, the experiments in the Literature that test this prediction have produced contradictory results. In this Letter, we describe new polarized transient hole-burning experiments on solvated electrons in both water and methanol. Although we chose excitation wavelengths that should have ...