We report an amidinato ligand-supported series of magnesium complexes obtained from the insertion of a magnesium-carbon bond into a carbon-nitrogen double bond of different carbodiimides and α-diimine ligands. The magnesium complexes [Mg(CH2Ph){CyN[double bond, length as m-dash]C(CH2Ph)NCy}]2 (), [Mg(CH2Ph){(i)PrN[double bond, length as m-dash]C(CH2Ph)N(i)Pr}]2 () and the homoleptic [Mg{(t)BuN[...

This study investigated the effect of Er:YAG laser on bonding to dentin and the interaction pattern of different adhesive systems with the lased substrate. Tensile bond strength of a self-etching [Clearfil SE Bond (CSEB)] and two total-etch [Single Bond (SB) and Gluma One Bond (GOB)] systems to lased and non-lased dentin was evaluated and the adhesive interface morphology was examined by SEM. D...

PURPOSE This in-vitro study evaluated shear bond strength and analyzed, via scanning electron microscopy, enamel prepared for pit and fissure sealant placement. Various surface pretreatment methods were conducted prior to short-term (72-hour) and long-term (120-day) analysis. METHOD Six treatment groups of 14 teeth, having 28 bonding surfaces (buccal and lingual) were treated. Cylinders of De...

Multi-mode universal adhesives (UA) are indicated as either self-etch or etch-and-rinse adhesives, and manufacturers also recommend an alternative ‘selective enamel etch’ technique. Currently available laboratory data support phosphoric acid selective etching of enamel prior to use of UA to improve bond strength. In another way to improve adhesion to enamel of UA without the use of phosphoric a...

We study the weak limit of arboreal gas along any exhaustion a regular tree with wired boundary conditions. prove that this exists, does not depend on choice exhaustion, and undergoes phase transition. Below at criticality, we model is equivalent to bond percolation. Above characterise as superposition critical percolation random collection infinite one-ended paths. This provides simple example...

background and aims: we aimed to assess the bond strength of composite resin to three pulp capping biomaterials; proroot mineral trioxide aggregate (pmta), root mta (rmta) and calcium enriched mixture (cem), using three bonding systems [a total etch (single bond) and two self-etch systems (protect bond and se bond)]. materials and methods: ninety acrylic moulds containing a 6×2 mm hole were div...

The zinc(II) atom in the title compound, [Zn(C48H31N4)(CF3SO3)](CF3SO3)·1.5CH2Cl2, adopts a distorted five-coordinate square-pyramidal geometry. It is coordinated by one tri-fluoro-methane-sulfonate ligand and four N atoms of the N2-[(benzo[h]quinolin-2-yl)meth-yl]-N2'-[(benzo[h]quinolin-2-yl)methyl-idene]-1,1'-binaphthyl-2,2'-di-amine ligand. The complex is present as a single-stranded P-helim...

A new methodology to obtain reactivity indices has been defined. This is based on reactivity functions such as the Fukui function or the dual descriptor and makes it possible to project the information of reactivity functions over molecular orbitals instead of the atoms of the molecule (atomic reactivity indices). The methodology focuses on the molecule's natural bond orbitals (bond reactivity ...