1-Vinylpyrrole-2-carbaldehydes react with acetylene at atmospheric pressure in a NaOH/EtOH/DMSO system at 7-10 °C to afford 2-(1-hydroxypropyn-2-yl)-1-vinylpyrroles in 53-94% yield. Thus, the first base-mediated direct ethynylation of pyrrolecarbaldehydes with free acetylene under modified conditions of the Favorsky reaction has been implemented to pave an expedient route to important biomolecu...

Transitions from normal-mode to local-mode states in the two bending oscillations of acetylene observed in spectroscopic studies, as well as the existence of localized vibrational states in vinylidene above the isomerization barrier to acetylene, are examined by constructing continuation/ bifurcation diagrams of periodic orbits on a global potential-energy surface. The principal families of per...

Effects of various factors affecting the rate of Carbon Nanotubes (CNTs) produced in a Swirled Floating Catalyst Chemical Vapour Deposition (SFCCVD) reactor were investigated. This study was performed in a vertical silica tube plug flow reactor developed by Iyuke at this University. Transmission Electron Microscopy (TEM) images revealed that both Single–Walled and Multi–Walled Carbon Nanotubes ...

Laminar flame speeds of mixtures of ethane, ethylene, acetylene, and carbon monoxide with small amounts of hydrogen addition at both atmospheric and elevated pressures were experimentally and computationally determined. It was found that the approximate linear correlation identified previously between the laminar flame speeds and an appropriate definition of the amount of hydrogen addition for ...

Understanding the mechanism of gas-sorbent interactions is of fundamental importance for the design of improved gas storage materials. Here we report the binding domains of carbon dioxide and acetylene in a tetra-amide functionalized metal-organic framework, MFM-188, at crystallographic resolution. Although exhibiting moderate porosity, desolvated MFM-188a exhibits exceptionally high carbon dio...

A method for acetylene inhibition measurements of denitrification in the field using micrometeorological techniques is presented. It is based on the monitoring of flux ratios from small (<5 m2) microplots. The method measures concentration profiles close to the surface, and from these the ratio of gradients, which can be assumed to be equal to the ratio of fluxes, is calculated. Acetylene has b...

The dipotassium salts of maleic, fumaric and acetylenedicarboxylic acids were electrooxidized and the reaction products were analyzed qualitatively and quantitatively by UV/VIS and FT-IR spectroscopy. Acetylene, carbon dioxide and carbon monoxide, along with polyynes, are the products obtained from maleic and fumaric acids. The best acetylene yields are obtained from fumaric acid and not from m...