The aim of our study was to evaluate a model system by using iron in the peroxidation of plasma. Lipid peroxidation was monitored by fluorometric measurement of lipid peroxides (LPO). Plasma coincubated with Fe2+ and H2O2 had a 268% increase in plasma LPO after 1 h. The optimum concentrations were 0.42 mmol/L Fe2+ and 0.73 mol/L H2O2. Coincubation of plasma with these concentrations of Fe2+ and...

A two-dimensional numerical model incorporating solid mechanics, electrochemistry, mass diffusion, and ion migration processes is developed to investigate the load effect on crevice corrosion. The a transient of corrosion occurring in cracks 304 stainless steel dilute NaCl solution, interaction between stress electrochemical was considered. By solving multiphysical coupling COMSOL, applied crac...

The major problem with Carlin-type gold deposit flotation is that the high dolomite content in concentrate decreases quality of gold. Further, activation mechanisms involved are still not fully understood. Herein, correlation Fe2+ conversion xanthate adsorption and was investigated to reveal effect embedded pyrite. Flotation tests suggested rather than Fe3+ improved floatability from 20% 45%. C...

Explorations of phases in the quaternary Fe(III)-B(III)-P(V)-O system prepared by the high temperature solution growth (HTSG) method led to single-crystal growth of anhydrous diiron(III) borotriphosphate, Fe(2)[BP(3)O(12)]. This phase has been synthesized previously as a microcrystalline material and its structure refined in space group P3 from powder X-ray diffraction data using the Rietveld m...

Certain DNA sequences are known to be unusually sensitive to nicking via the Fe2+-mediated Fenton reaction. Most notable are a purine nucleotide followed by three or more G residues, RGGG, and purine nucleotides flanking a TG combination, RTGR. Our laboratory previously demonstrated that nicking in the RGGG sequences occurs preferentially 5' to a G residue with the nicking probability decreasin...

In order to survive in an oxygen environment, aerobic organisms have developed numerous mechanisms to protect against oxygen radicals and singlet oxygen. One such mechanism, which appears to have attained particular significance during primate evolution, is the direct scavenging of oxygen radicals, singlet oxygen, oxo-haem oxidants and hydroperoxyl radicals by uric acid. In the present paper we...

The metal-organic framework Fe2(dobdc) (dobdc(4-) = 2,5-dioxido-1,4-benzenedicarboxylate), often referred to as Fe-MOF-74, possesses many interesting properties such as a high selectivity in olefin/paraffin separations. This compound contains open-shell Fe(II) ions with open coordination sites which may have large single-ion magnetic anisotropies, as well as isotropic couplings between the near...

Zinc-ion batteries have attracted great interest for their low cost, safety, and high energy density. Recently, Zn3V4(PO4)6 has been reported to be a promising cathode material zinc-ion batteries. The defect chemistry, diffusion of Zn-ions, solution dopants are examined by advanced simulation techniques. results show that the most favorable intrinsic is Zn-V anti-site. A zig-zag pattern long-ra...

Divalent ions of the first series transition elements and Hg were introduced into a cadmium hydroxyapatite Cd5 (P04) 30H by replacing a part of Cd2+, and the effects on the crystal growths and the structural changes were studied. Cd2+ can be exchanged with Mn2+ up to about 30 mol %, with N¡Z+or Hg2+ up to about 10 mol %, and with a little amount of Fe2+ or Cu2+. It was found that Cd5 (PO.)sOH f...