Perovskite oxides hosting ferroelectricity are particularly important materials for modern technologies. The ferroelectric transition in the well-known oxides BaTiO3 and PbTiO3 is realized by softening of a vibration mode in the cubic perovskite structure. For most perovskite oxides, octahedral-site tilting systems are developed to accommodate the bonding mismatch due to a geometric tolerance f...

Keywords: HfO 2 Analytical model Surface potential Ferroelectric Nonvolatile memory Fe-TFET a b s t r a c t The implementation and operation of the nonvolatile ferroelectric memory (NVM) tunnel field effect transistors with silicon-doped HfO 2 is proposed and theoretically examined for the first time, showing that ferroelectric nonvolatile tunnel field effect transistor (Fe-TFET) can operate as...

As a room temperature multi-ferroic with coexisting anti-ferromagnetic, ferroelectric and ferroelastic orders, BiFeO(3) has been extensively studied to realize magnetoelectric devices that enable manipulation of magnetic ordering by an electric field. Moreover, BiFeO(3) is a promising candidate for ferroelectric memory devices because it has the largest remanent polarization (P(r)>100 μC cm(-2)...

Halide perovskite (HaP) semiconductors are revolutionizing photovoltaic (PV) solar energy conversion by showing remarkable performance of solar cells made with HaPs, especially tetragonal methylammonium lead triiodide (MAPbI3). In particular, the low voltage loss of these cells implies a remarkably low recombination rate of photogenerated carriers. It was suggested that low recombination can be...

In a recent letter [Phys. Rev. Lett. 75, 2360 (1996)] we briefly discussed the existence and nature of ferroelectric order in positionally disordered dipolar materials. Here we report further results and give a complete description of our work. Simulations of randomly frozen and dynamically disordered dipolar soft spheres are used to study ferroelectric ordering in non-crystalline systems. We a...

Currently, an intensive search for high-performance lead-free ferroelectric materials is taking place. ABO₃ perovskites (A = Ba, Bi, Ca, K and Na; B = Fe, Nb, Ti, and Zr) appear as promising candidates. Understanding the structure-function relationship is mandatory, and, in this field, the roles of long- and short-range crystal orders and interactions are decisive. In this review, recent advanc...

Consider an insulating system with non-zero spontaneous polarization Ps (dielectric di‐ pole moment per unit volume). If an applied external electric field E that is greater than the so-called coercive field Ec can reverse Ps then our system is a ferroelectric system. Ferroelectricity has a long and exciting history described in [1,2]. In the beginning of its historical development (the Rochell...

properties in ferroelectric superlattices I. B. Misirlioglu, M. T. Kesim, and S. P. Alpay Faculty of Engineering and Natural Sciences, Sabanci University, Tuzla/Orhanli, 34956 Istanbul, Turkey Department of Materials Science and Engineering and Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269, USA Department of Physics, University of Connecticut, Storrs, Conn...

There has been tremendous research activity in the field of magnetoelectric (ME) multiferroics after Kimura et al (2003 Nature 426 55) showed that antiferromagnetic and ferroelectric orders coexist in orthorhombically distorted perovskite TbMnO3 and are strongly coupled. It is now generally accepted that ferroelectricity in TbMnO3 is induced by magnetic long-range order that breaks the symmetry...

A synthetic method for the end-functionalization of vinylidene fluoride oligomers (OVDF) via a radical reaction between terminal olefins and I-OVDF is described. The method shows a wide substrate scope and excellent conversions, and permits the preparation of different disc-shaped cores such as benzene-1,3,5-tricarboxamides (BTAs), perylenes bisimide (PBI), and phthalocyanines (Pc) bearing thre...