We report the first extensive study of stellar Rb abundances. High-resolution spectra have been used to determine, or set upper limits on, the abundances of this heavy element and the associated elements Y, Zr, and Ba in 44 dwarfs and giants with metallicities spanning the range −2.0 < [Fe/H] < 0.0. In metal-deficient stars Rb is systematically overabundant relative to Fe; we find an average [R...