International Symposium on Resource and Environmental Monitoring { Local, Regional, Global Study of Sealed Surfaces and Diurnal Temperature Variations in Urban Environments with Airborne Scanner Data Ramon Franck, Boris Prinz, Rafael Wiemker, Hartwig Spitzer II. Institut f ur Experimentalphysik, CENSIS Universit at Hamburg Mail address: KOGS, Vogt-K olln-Str. 30, 22527 Hamburg, Germany WWW: ...

Toeplitz matrices have applications to different problems of statistical mechanics. Recently it was used for calculation of entanglement entropy in exactly solvable models including spin chains. We use Fisher-Hartwig formula to calculate entanglement entropy [as well as Rényi entropy] of large block of spins in the ground state of XY spin chain. In the end of the paper we announce our recent re...

The asymptotics of the Schatten norms of finite Toeplitz matrices generated by functions with a Fisher-Hartwig singularity are described as the matrix dimension n goes to infinity. The message of the paper is to reveal some kind of a kink: the pth Schatten norm increases as n to the power 1/p before the singularity reaches a critical point and as n to an exponent depending on the singularity be...

A new [2.2]paracyclophane-based electron-rich and sterically bulky monophosphine ligand has been synthesized by an efficient and straightforward method. When combined with palladium, this ligand shows excellent performance in the Buchwald-Hartwig amination and Suzuki-Miyaura coupling reactions of various aryl chlorides. In both types of reactions, ortho-substituted, deactivated aryl chlorides a...

Halogenated quinazolinones and quinazolines are versatile synthetic intermediates for the metal-catalyzed carbon-carbon bond formation reactions such as the Kumada, Stille, Negishi, Sonogashira, Suzuki-Miyaura and Heck cross-coupling reactions or carbon-heteroatom bond formation via the Buchwald-Hartwig cross-coupling to yield novel polysubstituted derivatives. This review presents an overview ...

Two divergent synthetic routes are reported offering access to four quinolone natural products from Pseudonocardia sp. CL38489. Key steps to the natural products involved a regioselective epoxidation, an intramolecular Buchwald-Hartwig amination and a final acid-catalysed 1,3-allylic-alcohol rearrangement to give two of the natural products in one step. This study completes the synthesis of all...

Aim: Adverse drug reaction (ADR) reporting and monitoring activities are of vital importance for patient safety. It is a predominant ubiquitous preventable clinical issue. This study was conducted to assess the ADR in various departments. Methods: Standard forms were filled up by healthcare workers patients from January 2020 December 2021 different The causality appraisal ADRs finished utilizin...

Buchwald–Hartwig amination is one of the most important methods for synthesis N-arylamines and widely employed potential pharmaceuticals, natural products, other fine chemicals. The reaction usually uses a Pd(0) catalyst such as Pd(dba)2 (±)-BINAP in presence base, toluene commonly used solvent. However, there are significant safety, toxicological, environmental hazards associated with use tolu...

Introduction: The aim was to assess, categorize and analyze the adverse drug reactions among geriatric patients in a tertiary care hospital. 
 Methods: All of reported at Adverse Drug Reaction Monitoring Center, Sri Venkateswara Medical College, Tirupati, under Pharmacovigilance programme India, during September 2016 January 2018 were identified evaluated. A retrospective analysis carried ...

we call a the symbol of the sequence {Tn} and denote Tn by Tn(a). The case where a is in L∞(T) is easy, since then ‖Tn(a)‖ → ‖a‖∞ as n → ∞. Things are more complicated for a ∈ L(T) \L∞(T). We here focus our attention on so-called FisherHartwig symbols with a single singularity, that is, we consider functions a of the form a(t) = |t− t0|φβ,t0(t)b(t) (t ∈ T) where t0 ∈ T, α is a complex number su...