Aromatic aldehydes are efficiently condensed with 2'-hydroxyacetophenone by polymer-supported basic ionic liquid as an excellent heterogeneous catalyst utilizing the Claisen–Schmidt reaction. Microwave irradiation has been employed, providing flavanone in good yield and short reaction time.

Homogeneous nucleation at high supersaturation of vapor and heterogeneous nucleation on microscopic wettable particles are studied on the basis of Lennard-Jones model system. A hybrid classical thermodynamics and density-functional theory (DFT) approach is undertaken to treat the nucleation problems. Local-density approximation and weighted-density approximation are employed within the framewor...

Pressure reduction in liquids may result vaporization and bubble formation—a process known as cavitation. It is commonly observed hydraulic machinery, ship propellers even the context of medical therapy within human body. Although cavitation be beneficial for removal malign tissue, many cases it unwanted due to its ability erode nearly any material close contact. The current understanding that ...

The focus of the present study is liquid-phase oxidation alkylaromatic hydrocarbons, particularly that ethylbenzene, in presence cobalt-based polymer complexes tuned to ethylbenzene and obtained based on cobalt salts a copolymer diethyl ether phenylphosphonic acid with acrylic acid. reaction was carried out without solvent at atmospheric pressure 900C temperature glass temperature-controlled eq...

A fluorocarbon and hydrocarbon organic solvent mixture is known as a temperature-induced phase-separation solution. When a mixed solution of tetradecafluorohexane as a fluorocarbon organic solvent and hexane as a hydrocarbon organic solvent (e.g., 71:29 volume ratio) was delivered in a capillary tube that was controlled at 10°C, the tube radial distribution phenomenon (TRDP) of the solvents was...

This paper presents and analyzes two different strategies of heterogeneous distribution of computations solving dense linear algebra problems on heterogeneous networks of computers. The first strategy is based on heterogeneous distribution of processes over processors and homogeneous block cyclic distribution of data over the processes. The second is based on homogeneous distribution of process...

The homogeneous and heterogeneous nucleation of a Lennard-Jones liquid is investigated using the umbrella sampling method. The free energy cost of forming a nucleating droplet is determined as a function of the quench depth, and the saddle point nature of the droplets is verified using an intervention technique. The structure and symmetry of the nucleating droplets are found for a range of temp...

Specific reversed-phase high-performance liquid chromatography conditions are reported for the analysis of recombinant and native human luteinizing hormone (hLH) and human chorionic gonadotropin (hCG) preparations. Heterodimeric hLH, hCG and their alpha- and beta-subunits migrated with significantly different retention times (t(R)) in the following order of increasing hydrophobicity: alpha-hCG<...