In this article, we analyze a model of the incipient dynamics of gel swelling, and perform numerical simulations. The governing system consists of balance laws for a mixture of nonlinear elastic solid and solvent yielding effective equations for the gel. We discuss the multiscale nature of the problem and identify physically realistic regimes. The mixing mechanism is based on the Flory-Huggins ...

Modern physiologically based models of the binaural system incorporate internal delay lines in the pathways from left and right peripheries to central processing nuclei. Different binaural models for the formation of dichotic pitch employ these delay lines in different ways. Consequently, the different models make different predictions for the relative strengths of dichotic pitches made with pa...

Mixtures containing compounds that undergo hydrogen bonding show large deviations from ideal behavior. These deviations can be accounted for through chemical theory, according to which the formation of a hydrogen bond can be treated as a chemical reaction. This chemical equilibrium needs to be taken into account when applying stability criteria and carrying out phase equilibrium calculations. I...

The phase behavior of aqueous mixtures of gelatin and oligosaccharides above their gelation temperature is investigated experimentally, and rationalized according to a simple multicomponent Flory–Huggins model. When the gelatin is only weakly charged, entropic considerations dominate and it is found that the cloud point curve of the mixtures is extremely sensitive to the molecular weight distri...

Transport of liquids by pervaporation takes place by a solution-diffusion mechanism. In order to investigate the “solution part” of this transport model, preferential sorption has been compared with preferential permeability. Sorption equilibria and pervaporation experiments for the systems water-ethanol-cellulose acetate, water-ethanol-polyacrylonitrile and water-ethanol-polysulfone have been ...

We show that a film of a suspension of polymer grafted nanoparticles on a liquid substrate can be employed to create two-dimensional nanostructures with a remarkable variation in the pattern length scales. The presented experiments also reveal the emergence of concentration-dependent bimodal patterns as well as re-entrant behaviour that involves length scales due to dewetting and compositional ...

Gas chromatography used to calculate the specific retention volume of several hydrocarbons in different chromatographic liquid phases (Squalane, Carbowax-400, Carbowax-1500, Carbowax-4000, Amine220, Dinonyl phthalate, Tributyl phosphate and Trixylenyl phosphate). Some thermodynamic parameters, such as enthalpy of sorption and Flory-Huggins parameters relating the interaction between liquid phas...

Polymer-polymer complexation in solvent is studied using an extension of the self-consistent field theory. The model polymers are capable of forming ladder-like duplex structures. The duplex formation occurs with an abrupt change of entropy, resulting in a first-order transition. Moreover, the complexation can be stabilized by solvent-polymer interactions, instead of the usual specific binding ...

Polymeric mixtures are important materials, but the control and understanding of mixing behaviour poses problems. The original Flory-Huggins theoretical approach, using a lattice model to compute the statistical thermodynamics, provides the basic understanding of the thermodynamic processes involved but is deficient in describing most real systems, and has little or no predictive capability. We...

Using the Flory-Huggins lattice model, we investigate the threading-unthreading equilibrium in a solution of linear flexible polymer chains and molecular nanotubes formed by covalently bonding the ringlike molecules, such as cyclodextrins (CDs). It is found that the threading-unthreading equilibrium depends on the temperature and the molar concentrations of the ringlike molecules and polymer ch...