Scientific knowledge of natural clathrate hydrates has grown enormously over the past decade, with spectacular new findings of large exposures of complex hydrates on the sea floor, the development of new tools for examining the solid phase in situ, significant progress in modeling natural hydrate systems, and the discovery of exotic hydrates associated with sea floor venting of liquid CO2. Majo...

The water-gas relative permeability is an important parameter to characterize multiphase flow in sediments. To study the of hydrate-bearing porous media, simulations were carried out at pore scale using lattice Boltzmann method. effects hydrate saturation and hydrate-growth habits on permeability, which scaled by considering only, evaluated a two-dimensional medium. Results show that increase c...

Blockage of pipelines by formation and accumulation of clathrate hydrates of natural gases (also called gas hydrates) can compromise project safety and economics in oil and gas operations, particularly at high pressures and low temperatures such as those found in subsea or arctic environments. Cyclopentane (CyC5) hydrate has attracted interest as a model system for studying natural gas hydrates...

One of the new approaches for capturing carbon dioxide from treated flue gases (post-combustion capture) is based on gas hydrate crystallization. The basis for the separation or capture of the CO(2) is the fact that the carbon dioxide content of gas hydrate crystals is different than that of the flue gas. When a gas mixture of CO(2) and H(2) forms gas hydrates the CO(2) prefers to partition in ...

[1] During sea-level drop, water and gas pressures within oceanic hydrate systems can exceed the total vertical stress and this can drive slope failure and gas venting. We investigate this behavior with a multi-phase fluid and heat flow model. During sea-level drop, fluid pressures drop much less than the total stress due to both the high gas compressibility and hydrate dissociation. In permeab...

An understanding of the physical properties of hydrate-bearing sediments is important for interpretation of geophysical data collected in field settings, borehole and slope stability analyses, and reservoir simulation and production models. Yet current knowledge of geophysical and geotechnical properties of hydratebearing sediments is still largely derived from laboratory experiments conducted ...

Cryogenic scanning electron microscopy provides an excellent means for examining phase distributions, grain morphologies, and grain contacts within gas-hydrate-bearing samples of both natural and laboratory origin. Here, recovered samples from JAPEX/JNOC/GSC et al. Mallik 5L-38 are imaged, and comparisons are made between the geometrical arrangement and appearance of the gas hydrate ± ice phase...

Field experiments were conducted to test ideas for fossil fuel carbon dioxide ocean disposal as a solid hydrate at depths ranging from 349 to 3627 meters and from 8 degrees to 1.6 degrees C. Hydrate formed instantly from the gas phase at 349 meters but then decomposed rapidly in ambient seawater. At 3627 meters, the seawater-carbon dioxide interface rose rapidly because of massive hydrate forma...

The SPARC software program and comparative density functional theory (DFT) calculations were used to investigate the aqueous phase hydration equilibrium constants (Khyd) of perfluoroalkyl aldehydes (PFAlds) and n:2 fluorotelomer aldehydes (FTAlds). Both classes are degradation products of known industrial compounds and environmental contaminants such as fluorotelomer alcohols, iodides, acrylate...

Gas hydrates are systems of prime importance. In particular, hydrogen hydrates are potential materials of icy satellites and comets, and may be used for hydrogen storage. We explore the H₂O-H₂ system at pressures in the range 0-100 GPa with ab initio variable-composition evolutionary simulations. According to our calculation and previous experiments, the H₂O-H₂ system undergoes a series of tran...