Superadiabatic Partial Oxidation for Hydrogen and Sulfur Production from Hydrogen Sulfide The Gas Technology Institute has been investigating superadiabatic partial oxidation concepts to not only develop novel, cost-effective processes to recover hydrogen and sulfur from hydrogen sulfide, but also produce hydrogen from natural gas and other liquid hydrocarbons, and gasify solid feedstocks, incl...

Kligler and Triple Sugar Iron (TSI) media have been considered to be interchangeable for the purpose of detecting hydrogen sulfide production in the family Enterobacteriaceae. Contrary evidence is presented in this report. From various sources, 11 cultures were isolated which yielded a positive hydrogen sulfide reaction on Kligler medium and a negative reaction on TSI. Biochemically, these cult...

Palladium-copper alloys continue to be of interest for hydrogen membrane applications because of their high catalytic activity for hydrogen dissociation, high hydrogen permeability, robustness, and degradation resistance in the presence of sulfur-containing compounds. This sulfur tolerance makes these alloys attractive for membrane applications where sulfur compounds are likely to be present, s...

this paper is a preliminary communication of a study on removal and recovery of heavy metalsfrom industrial waste waters using electro-coagulation (ec) technique. the larger study envisages use of solarenergy for producing the d.c. current, and simple chemical methods of standard methods in chemistry like useof hydrochloric acid, hydrogen sulfide, collection of precipitate, incineration and get...

Hydrogen Sulfide. Hydrogen sulfide (H2S) is a colorless gas with a characteristic odor of rotten eggs. It naturally occurs in the gases from volcanoes, sulfur springs, undersea vents, swamps, stagnant bodies of water, and in crude petroleum and natural gas. Additionally, bacteria, fungi, and actinomycetes release hydrogen sulfide during the decomposition of sulfur-containing proteins and by the...

Kinetics and stoichiometry of aerobic chemical and biological sulfide oxidation in wastewater from sewer networks were studied. In this respect, the effects of temperature and pH were investigated in the ranges 10 to 20 degrees C and 5 to 9, respectively. The temperature dependency of sulfide oxidation kinetics was described using an Arrhenius relationship. The effect of pH on the rate of chemi...

The last couple of years have witnessed the coming together of several initially unconnected lines of investigation which now link natural sulfur products to hydrogen sulfide release and wide ranging cardiovascular protection. It has become apparent that sulfur compounds contained within garlic, onions, mushrooms and various edible beans and fruits may be transformed chemically or enzymatically...

cellulose sulfuric acid as a bio-polymer based solid catalyst efficiently catalyzes the selectively oxidation of sulfides to sulfoxides and thiols to disulfides using hydrogen peroxide as a green oxidant with good yields at room temperature. the developed method offers a number of advantages such as high selectivity, mild reaction conditions, simple operation, cleaner reaction profiles, low cos...

Inflammation plays a critical role in kidney ischemia-reperfusion injury but mechanisms of increased proinflammatory cytokine expression are not completely understood. Kidney has a high expression of cystathionine-β-synthase (CBS) and cystathionine-γ-lyase (CSE) that can synthesize hydrogen sulfide. CBE and CSE are also responsible for the synthesis of cysteine, an essential precursor for gluta...

Polymorphonuclear leukocytes (PMN) isolated from human blood were exposed to various levels of hydrogen sulfide. The effect on respiratory burst, myeloperoxidase activity, and capacity to phagocytose and kill bacteria were studied. A 1-h exposure of the PMN to 1 mM sulfide did not decrease their myeloperoxidase activity or their capacity to initiate a respiratory burst. Actually the products of...