Thermal electron attachment to the radical species C2F3 and C2F5 has been studied over the temperature range 300-890 K using the Variable Electron and Neutral Density Attachment Mass Spectrometry technique. Both radicals exclusively undergo dissociative attachment to yield F(-). The rate constant for C2F5 shows little dependence over the temperature range, remaining ~4 × 10(-9) cm(3) s(-1). The...

Until now, all methods for temperature sensing in capillary electrophoresis (CE) relied on molecular probes with temperature-dependent spectral/optical properties. Here we introduce a nonspectroscopic approach to determining temperature in CE. It is based on measuring a temperature-dependent rate constant of complex dissociation by means of a kinetic CE method known as nonequilibrium capillary ...

An in situ respirometric technique was applied to a sequential biofilm batch reactor treating a synthetic wastewater containing acetate. In this reactor, inoculated with mixed liquor from a wastewater plant, unglazed ceramic tiles were used as support media while maintaining complete mixing regime. A total of 8 kinetic and stoichiometric parameters were determined by in situ pulse respirometry;...

Extreme instability of pyrimidine motif triplex DNA at physiological pH severely limits its use for artificial control of gene expression in vivo. Stabilization of the pyrimidine motif triplex at physiological pH is therefore of great importance in improving its therapeutic potential. To this end, isothermal titration calorimetry interaction analysis system and electrophoretic mobility shift as...

3 H-Spiroperidol, a butyrophenone antipsychotic agent, binds specifically and with high affinity to neuroleptic receptors in the 3 corpus striatum and substantia nigra. Scatchard analysis of Hspiroperidol isotherms in the rat striatum revealed a dissociation constant (KQ) of 30 pM and a total receptor density (Bmax) of 430 fmoles/mg protein. In the substantia nigra, the and Bmax values were 42 ...

We demonstrate that the latest constraints on inflationary observables, namely tensor-to-scalar ratio $r$ and scalar spectral index $n_{_S}$, from Cosmic Background Radiation (CMB) observations are already strong enough to rule out model of a field with power law potential even in presence kinetic coupling gravity positive constant. The case for negative constant needs special treatment.

In this study, kinetics of biological carbon, nitrogen, and phosphorous removal from a synthetic wastewater in an integrated rotating biological contactoractivated sludge system was investigated. The experimental data obtained from varying four significant independent factors viz., hydraulic retention time, chemical oxygen demand for nitrogen to phosphorus ratio, internal recirculation from aer...

The kinetic mechanism of the binding and release of calcium by troponin and by the complexes troponin: tropomyosin, troponin:tropomyosin:actin, and troponin (TN)-tropomyosin (TM)-actin:myosin subfraction 1 (SF-1) was investigated using troponin labeled on the TN-I subunit with the fluorophore 4-(N-iodoac etoxyethyl-N-methyl)-7-nitrobenz-2-oxa-1,3-diazole. The apparent association constant is fi...

This thesis has investigated oxygen uptake ( i r02) kinetic regulation during whole body exercise by investigating not only the breath-by-breath V O ~ response to a change in work rate but also incorporating an examination of data analysis processes and simulation of a physiological V O ~ model. Five experiments have been completed to answer the following questions: Experiment 1: What effects d...

Beltrami states for compressible barotropic flows are deduced by minimizing the total kinetic energy while keeping the total helicity constant. A Hamiltonian basis for these Beltrami states is also sketched.