Multiphoton/tunnel ionization of benzene, interacting with strong Ti:sapphire laser pulses, to doubly charged ions was studied. In contrast to previously published results on multiphoton/tunnel ionization of atoms and molecules, it was demonstrated that double ionization of benzene occurs mainly through non-sequential processes.

The dynamics of electrons ionized from high charge states by lasers with intensity >10(20) W/cm(2) have been studied. At these intensities vxB forces drive the electrons subsequent to ionization in a trajectory nearly parallel to the laser propagation direction. This gives rise to large energy gains as the electron rides in phase with the laser field over a long distance. Monte Carlo simulation...

Laser desorption followed by jet-cooling allows wavelength-selective as well as massselective detection of molecules desorbed from a surface without fragmentation. The cooling characteristics and detection sensitivity of laser desorption jet-cooling of organic molecules are investigated. From the rotational contour of the electronic origin of the $1 ~-So transition of laserdesorbed anthracene, ...

Quantum calculations of a (1+1)-dimensional model for double ionization in strong laser fields are used to trace the time evolution from the ground state through ionization and rescattering to the two-electron escape. The subspace of symmetric escape, a prime characteristic of nonsequential double ionization, remains accessible by a judicious choice of 1D coordinates for the electrons. The time...

Mid-infrared laser ablation of water-rich targets at the maximum of the 2.94 μm absorption band is a two-step process initiated by phase explosion followed by recoil pressure induced material ejection. Particulates and/or droplets ejected by this high temperature high pressure process can be ionized for mass spectrometry by charged droplets from an electrospray. In order to gauge the internal e...

Mid-infrared laser ablation of water-rich targets at the maximum of the 2.94 mm absorption band is a two-step process initiated by phase explosion followed by recoil pressure induced material ejection. Particulates and/or droplets ejected by this high temperature high pressure process can be ionized for mass spectrometry by charged droplets from an electrospray. In order to gauge the internal e...

We study the order in which a strong laser field removes multiple electrons from a van der Waals (vdW) cluster. The N2Ar, with an equilibrium T-shaped geometry, contains both a covalent and a vdW bond and serves as a simple yet rich example. Interestingly, the fragmenting double and triple ionizations of N2Ar with vdW bond breaking are favored when the vdW bond is aligned along the laser field ...

The double ionization of argon and xenon in an intense laser field has been studied in detail using an electron-ion coincidence technique. The observed double ionization electron spectra in xenon show resonancelike structures here resolved for the first time. In argon, the featureless spectra are consistent with rescattering. This represents a clear transition in the dynamics of strong-field do...

To date, mass spectrometric analysis of biomolecules has been primarily performed with either matrix-assisted laser desorption/ionization (MALDI) or electrospray ionization (ESI). In this work, ultrasound produced by a simple piezoelectric device is shown as an alternative method for soft ionization of biomolecules. Precursor ions of proteins, saccharides and fatty acids showed little fragmenta...

The interaction of intense, femtosecond laser pulses with a dielectric medium is examined using a numerical simulation. The simulation uses the one-dimensional electromagnetic wave equation to model laser pulse propagation. In addition, it includes multiphoton ionization, electron attachment, Ohmic heating of free electrons, and temperature-dependent collisional ionization. Laser pulses conside...