Reducing the high charge potential is a crucial concern in advancing the performance of lithium-oxygen batteries. Here, for water-containing lithium-oxygen batteries with lithium hydroxide products, we find that a hydrogen peroxide aqueous solution added in the electrolyte can effectively promote the decomposition of lithium hydroxide compounds at the ultralow charge potential on a catalyst-fre...

In typical charge and discharge cycling, electrodes may exhibit metastable phases with unusual ordering to repeatedly host and extract lithium-ion and electrons. This is a clear consequence of not enough time and/or energy available for such metastable phases to relax and transform into their equilibrium counterparts (1). Such metastable structures may exist only for a short duration, which mak...

In this research, inorganic material type and content influence on coating of commercially available polypropylene (PP) separator were studied for improving its performance and safety as lithium ion battery separator. Heat-resistant nanopowders of Al2O3, SiO2 and ZrO2 were coated using polyvinylidene fluoride (PVDF) binder. Coating effects on the separators morphology, wettability, high tempera...

Large-scale energy storage represents a key challenge for renewable energy and new systems with low cost, high energy density and long cycle life are desired. In this article, we develop a new lithium/ polysulfide (Li/PS) semi-liquid battery for large-scale energy storage, with lithium polysulfide (Li2S8) in ether solvent as a catholyte and metallic lithium as an anode. Unlike previous work on ...

: [email protected] Abstract Three different morphology controlled copper oxide materials (porous microspheres, flower-like, and thorn-like CuO) were prepared by facile and environmentally friendly processes, which were further investigated for their electrochemical properties and performance at lithium-ion battery anodes. CuO microspheres were prepared by simply solution chemistry, whereas flow...

A closer look: Solid-state (7) Li and (17) O NMR spectroscopy is a valuable tool in the characterization of products formed in the lithium-oxygen battery, a necessary step in the development of a viable cell. Since lithium peroxide, the desired discharge product, has a unique (17) O NMR signature, it can be clearly identified.

Developing efficient catalyst for oxygen evolution reaction (OER) is essential for rechargeable Li-O2 battery. In our present work, porous LaNiO3 nanocubes were employed as electrocatalyst in Li-O2 battery cell. The as-prepared battery showed excellent charging performance with significantly reduced overpotential (3.40 V). The synergistic effect of porous structure, large specific surface area ...

A conducting lithium aluminum germanium phosphate (LAGP) glass-ceramic with a formula of Li1.5Al0.5Ge1.5(PO4)3 was synthesized by melt-quenching method and subsequent crystallization at 850 °C for 8 h. The prepared glass-ceramic was characterized using differential scanning calorimetry (DSC), X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and AC impedance techniqu...

DOI: 10.1002/aenm.201301329 Energy conversion and storage, [ 1–3 ] as the two most important technologies for energy, are usually two distinct processes that are performed by using two different and separated physical units, such as a piezoelectric nanogenerator and lithium-ion battery. [ 4–9 ] Recently, we presented a novel fundamental mechanism that directly hybridizes the two processes into ...