Abstract Background The nano-sized particles enhance the exposed surface area of active part catalyst, thereby increasing contact between precursors and catalyst considerably. In this study, nano-SiO 2 /1,5-diazabicyclo[4.3.0]non-5-en was synthesized, characterized used as a heterogeneous nanocatalyst for synthesis tetrahydrobenzo[ b ]pyran derivatives. Fourier Transform Infrared Spectroscopy, ...

Ni2+ supported on hydroxyapatite-core@shell γ-Fe2O3 nanoparticles (γ-Fe2O3@HAp-Ni2+) was found to be a useful catalyst for the synthesis of benzimidazole derivatives from o-phenylenediamine and aldehydes under solvent and solvent-free conditions at 80 °C. This reaction affords the corresponding benzimidazole derivatives compared with the classical reactions this method consistently gives a high...

In this paper, a new nano-size ionic liquid (nIL) has been synthesized from D-phenylalanine and oxalic acid (D-Phe-OX) via a simple procedure. The obtained nIL has been characterized by the fourier transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDAX), thermogravimetric analysis (TGA), nuclear magnetic resonance spectroscopy (1</sup...

Nanoparticle-based catalysts, or nanocatalysts, have been applied in various industrial sectors, including refineries, petrochemical plants, the pharmaceutical industry, the chemical industry, food processing, and environmental remediation. As a result, there is an increasing risk of human exposure to nanocatalysts. This review evaluates the toxicity of popular nanocatalysts applied in industri...

A new nanocatalyst which comprises gold particles (average size = (2.5 ± 1.3) nm) supported on intrinsically conductive polyaniline (PANI) was prepared via a sol-method. This Au/PANI catalyst was used for the first time in hydrogenation of the , -unsaturated aldehyde citral exhibiting high activity (93% conversion) and selectivity (76%) towards the products of C=O group hydrogenation, geraniol ...

In this paper, a new nano-size ionic liquid (nIL) has been synthesized from D-phenylalanine and oxalic acid (D-Phe-OX) via a simple procedure. The obtained nIL has been characterized by the fourier transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDAX), thermogravimetric analysis (TGA), nuclear magnetic resonance spectroscopy (1</sup...

A synergetic effect of nanocatalyst and ultrasonic irradiation was examined for the synthesis 4H-chromenes from benzaldehyde, cyclohexanone, malononitrile. It observed this contributory improved reaction that used highly pure products in short times highest yields. The nanocomposite includes guanidine anchored on to magnetic NiFe2O4 nanoparticles were as active base sonication compounds. produc...