Arsenic mobility in natural systems is often linked to iron and sulfur cycling at redox boundaries, apparently due to co-precipitation reactions of arsenic with poorly crystalline iron (oxy)hydroxides, iron monosulfides, and pyrite (e.g., Edenborn et al., 1986; Moore et al., 1988). The mobility of arsenic under anoxic, sulfate-reducing conditions is expected to be governed by interactions betwe...