Morphology evolution of the multicomponent metallic glass film obtained by radio frequency (RF) magnetron sputtering was investigated in the present work. Two modes of metallic glass sputtering were distinguished: smooth film mode and clustered film mode. The sputtering parameters, which have the most influence on the sputtering modes, were determined. As a result, amorphous Ni-Nb thin films wi...

This paper reports the design, making and characterisation of a series of Fe-based bulk metallic glass alloys with the aim of achieving the combined properties of high neutron absorption capability and sufficient glass forming ability. Synchrotron X-ray diffraction and pair distribution function methods were used to characterise the crystalline or amorphous states of the samples. Neutron transm...

Correction for 'Elastic strain effects on catalysis of a PdCuSi metallic glass thin film' by Yiyi Yang et al., Phys. Chem. Chem. Phys., 2015, 17, 1746-1754.

Recent progress in microand nanofabrication techniques enables the creation of hierarchically architected microlattices with dimensional control over six orders of magnitude, from centimeters down to nanometers. This hierarchical control facilitates the exploration of opportunities to exploit nano-sized material effects in structural materials. In this work, we present the fabrication, characte...

We report on the properties of one example of a new family of metallic alloys which exhibit excellent glass forming ability. The critical cooling rate to retain the glassy phase is of the order of 10 K/s or less. Large samples in the form of rods ranging up to 14 mm in diameter have been prepared by casting in silica containers. The undercooled liquid alloy has been studied over a wide range of...

We investigated structural disorder by a new structural parameter, quasi-nearest atom (QNA), in atomistic configurations of eight metallic glass-forming systems generated through molecular dynamics simulations at various temperatures. Structural analysis reveals that the scaled distribution of the number of QNA appears to be an universal property of metallic liquids and the spatial distribution...

Relaxation dynamics are the central topic in glassy physics. Recently, there is an emerging view that mechanical strain plays a similar role as temperature in altering the relaxation dynamics. Here, we report that mechanical strain in a model metallic glass modulates the relaxation dynamics in unexpected ways. We find that a large strain amplitude makes a fragile liquid become stronger, reduces...

The objective of this work is to develop bioactive glass coatings for metallic orthopedic implants. A new family of glasses in the SiO2–Na2O–K2O–CaO–MgO–P2O5 system has been synthesized and characterized. The glass properties (thermal expansion, softening and transformation temperatures, density and hardness) are in line with the predictions of established empirical models. The optimized firing...

An intrinsic plastic Cu(45)Zr(46)Al(7)Ti(2) bulk metallic glass (BMG) with high strength and superior compressive plastic strain of up to 32.5% was successfully fabricated by copper mold casting. The superior compressive plastic strain was attributed to a large amount of randomly distributed free volume induced by Ti minor alloying, which results in extensive shear band formation, branching, in...

The enthalpy relaxation behavior of Ti40Zr25Ni8Cu9Be18 bulk metallic glass follows the general characteristics of that for amorphous materials although its unique quenched-in nuclei/amorphous matrix structure: the annealing time dependence of recovery enthalpy follows a stretched exponential function with the mean relaxation time obeying an Arrhenius law, which may be due to the longer incubati...