نتایج جستجو برای: microwave spectroscopy

تعداد نتایج: 220219  

2015
Gregory B. Dudley Ranko Richert A. E. Stiegman

The use of microwave radiation to drive chemical reactions has become ubiquitous in almost all fields of chemistry. In all of these areas it is principally due to rapid and convenient heating resulting in significantly higher rates of reaction, with other advantages including enhanced product selectivity and control of materials properties. Although microwave heating continues to grow as an ena...

This paper reports the synthesis and characterization of photocatalyst CdS nanoparticles for investigation of photocatalytic degradation of 2,4,6-trichlorophenol. CdS nanoparticles were synthesized by the microwave-assisted sol-gel method and characterized by various techniques such as X-ray diffraction, filed emission scanning electron microscopy, energy dispersive spectroscopy, Fourier transf...

Journal: :Physical chemistry chemical physics : PCCP 2015
Yugo Tasei Fumikazu Tanigawa Izuru Kawamura Teruaki Fujito Motoyasu Sato Akira Naito

Microwave heating effects are widely used in the acceleration of organic, polymerization and enzymatic reactions. These effects are primarily caused by the local heating induced by microwave irradiation. However, the detailed molecular mechanisms associated with microwave heating effects on the chemical reactions are not yet well understood. This study investigated the microwave heating effect ...

2016
Fuminao Kishimoto Masayuki Matsuhisa Shinichiro Kawamura Satoshi Fujii Shuntaro Tsubaki Masato M. Maitani Eiichi Suzuki Yuji Wada

Various microwave effects on chemical reactions have been observed, reported and compared to those carried out under conventional heating. These effects are classified into thermal effects, which arise from the temperature rise caused by microwaves, and non-thermal effects, which are attributed to interactions between substances and the oscillating electromagnetic fields of microwaves. However,...

2012
Audrey Cottet

This article discusses how to demonstrate the entanglement of the split Cooper pairs produced in a doublequantum-dot based Cooper pair beam splitter (CPS), by performing the microwave spectroscopy of the CPS. More precisely, one can study the dc current response of such a CPS to two on-phase microwave gate irradiations applied to the two CPS dots. Some of the current peaks caused by the microwa...

Journal: :Physical chemistry chemical physics : PCCP 2009
Etienne Séguin Sébastien Thomas Philippe Bazin Gary Bond Carlos Henriques Frédéric Thibault-Starzyk

An improved micro-reactor cell for IR spectroscopic studies of heterogeneous catalysis was built around a 5.8 GHz microwave cavity. The reactor can operate at 20 bars and with conventional heating up to 720 K, with reactant gas flows velocities (GHSV) from 25,000 to 50,000 h(-1). The temperature of the sample under microwave irradiation was measured by time resolved IR emission spectroscopy. Th...

2013
Qi Zhang Shijun Zhang Liying Zhang

Polylactic acid (PLA) was successfully covalently grafted onto multi-walled carbon nanotubes (MWCNT) by microwave-assisted polymerization of lactide monomers. The final products MWCNT-g-PLA were characterized with Fourier-transform IR (FTIR), Raman spectroscopy, thermogravimetric analyses (TGA) and transmission electron microscopy (TEM). The results indicated PLA chain was covalently attached t...

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